A linearly programmable strategy for polymer elastomer mechanics†

Abstract

The mechanical properties of polymer elastomer materials, such as strength and ductility, play important roles in a wide range of applications, including the carrying of major equipment and the construction of infrastructure. However, owing to the widespread disordered physicochemical bonding and unpredictable internal phase separation phenomenon, traditional materials show a complex nonlinear correlation between the material structure and its performance, which makes it difficult to accurately adapt to the performance requirements of various specific application scenarios. In view of the above challenges, this paper innovatively proposes a strategy to achieve linear programmability in the mechanical properties of polymer elastomer materials. Instead of increasing the entropy value of the material, which may be brought about by the traditional physical composite method, this strategy adopts a unique path of introducing special dynamic chain segments (AlPUs). This innovative design leads to a highly ordered microscopic hydrogen bonding arrangement within the elastomer, which effectively reduces the free volume within the material, thus bringing the mechanical response of the material closer to the ideal state. Furthermore, by fine-tuning the content of material components, we are able to achieve linear control of key mechanical indexes, such as tensile strength and elongation at break, which is a significant advantage in terms of precision, range of adjustment, and versatility. The successful implementation of this work opens up a new way toward logical, fine and intelligent design and preparation of polymer materials, providing a solid materials science foundation and unlimited possibilities to promote technological innovation and development in the field of future major equipment and infrastructure.