Stage division and discharge mechanism characterization of micro-arc oxidation based on acoustic emission

IF 6.1 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2025-04-15 Epub Date: 2025-02-25 DOI:10.1016/j.surfcoat.2025.131964
Fengyuan Bao , Feng Li , Oleg Bashkov , Zhiyuan Wang , Ling Sun
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Abstract

Acoustic emission monitoring was conducted on the micro-arc oxidation process of the D16AT aluminum alloy plate with double-sided rolled pure aluminum in a silicate system electrolyte. Using the t-SNE algorithm, the recorded signals were classified based on the parameters of the acoustic emission signals. The analysis examined the regularities of the micro-arc oxidation stages under different current density conditions and their correspondence with signal characteristics and categories. Further discussion was held on the passivation and film formation mechanisms during the early, middle, and late stages of micro-arc oxidation. The effective film formation process of MAO was divided into four main stages: initial stage, weak micro-arc discharge, stable micro-arc discharge, and large arc discharge. Additionally, it included five sub-stages: conventional anodizing, weak glow discharge, transition from weak to strong glow discharge, transition from strong glow discharge to weak micro-arc discharge, and weak micro-arc discharge. The transition moments of these stages can be identified and determined by the frequency distribution of AE signals. As the current density increases, the discharge mechanism undergoes stage-wise changes. At different current densities, type-a signals primarily originate from gas glow discharge, while type-b signals are caused by breakdown at the bottom of the passivation film pores. Type-c signals mainly result from stable micro-arc discharge, and the increase in type-d signals marks the transition to a penetration-type strong discharge mechanism.

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基于声发射的微弧氧化阶段划分及放电机理表征
对D16AT铝合金板双面轧制纯铝在硅酸盐体系电解液中的微弧氧化过程进行了声发射监测。利用t-SNE算法,根据声发射信号的参数对录制信号进行分类。分析了不同电流密度条件下微弧氧化阶段的变化规律及其与信号特征和类别的对应关系。进一步讨论了微弧氧化初期、中期和后期的钝化和成膜机理。将MAO的有效成膜过程分为四个主要阶段:初始阶段、弱微弧放电阶段、稳定微弧放电阶段和大弧放电阶段。其中包括常规阳极氧化、弱辉光放电、弱辉光放电向强辉光放电过渡、强辉光放电向弱微弧放电过渡、弱微弧放电五个子阶段。通过声发射信号的频率分布可以识别和确定这些阶段的过渡矩。随着电流密度的增大,放电机制发生了逐级变化。在不同电流密度下,a类信号主要来源于气辉光放电,b类信号主要来源于钝化膜孔底部击穿。c型信号主要来自稳定的微弧放电,d型信号的增加标志着向穿透型强放电机制的过渡。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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