Unveiling the impact of 2-D materials on the gas sensing properties of metal oxides: A review

IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Journal of Environmental Chemical Engineering Pub Date : 2025-04-01 Epub Date: 2025-02-26 DOI:10.1016/j.jece.2025.115980
Sakshi Bisht , Neeraj Dhariwal , Preety Yadav , Meenu Chahar , Devender Singh , Vinod Kumar
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Abstract

The integration of 2D materials with metal oxides has emerged as a promising strategy to enhance gas sensing properties, offering significant improvements in sensitivity, selectivity, and response times. This review thus critically discusses the improvements on the gas sensor technologies enabled by integration of 2D materials like MoS2, g-C3N4, Mxene, rGO, CNT, PANI and Black Phosphorus into different metal oxide materials. Several synthesis techniques such as sol-gel process, hydrothermal process, chemical vapour deposition, sputtering and electrospinning have been presented with emphasis on their effects sensor characteristics. Creating heterojunctions and utilizing properties of 2D materials in the structure of the composite sensors enables them to display a high sensitivity to gas molecules, including their low concentrations and ambient temperature. These hybrid nanostructures offer improved surface area, active sites, and electronic properties, enabling the detection of low gas concentrations at room temperature. This paper offers a background for the current state, emerging prospects, and obstacles, as well as future advances regarding hybrid nanostructures, demonstrating the great opportunity they offer in the field of gas sensors for environmental and health concerns, and safety and industrial applications. The findings reveal their superior performance over conventional sensors, addressing key challenges in the field.
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揭示二维材料对金属氧化物气敏性能的影响:综述
2D材料与金属氧化物的集成已经成为增强气敏性能的一种很有前途的策略,在灵敏度、选择性和响应时间方面都有显着改善。因此,本文批判性地讨论了通过将二维材料(如MoS2, g-C3N4, Mxene, rGO, CNT, PANI和黑磷)集成到不同的金属氧化物材料中来实现的气体传感器技术的改进。介绍了溶胶-凝胶法、水热法、化学气相沉积法、溅射法和静电纺丝法等几种合成技术,重点介绍了它们的效应传感器特性。在复合传感器的结构中创建异质结并利用二维材料的特性,使它们对气体分子具有高灵敏度,包括它们的低浓度和环境温度。这些混合纳米结构提供了更好的表面积、活性位点和电子特性,能够在室温下检测低浓度气体。本文介绍了混合纳米结构的现状、新兴前景和障碍,以及未来的进展,展示了它们在环境和健康问题、安全和工业应用的气体传感器领域提供的巨大机会。研究结果表明,它们的性能优于传统传感器,解决了该领域的关键挑战。
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来源期刊
Journal of Environmental Chemical Engineering
Journal of Environmental Chemical Engineering Environmental Science-Pollution
CiteScore
11.40
自引率
6.50%
发文量
2017
审稿时长
27 days
期刊介绍: The Journal of Environmental Chemical Engineering (JECE) serves as a platform for the dissemination of original and innovative research focusing on the advancement of environmentally-friendly, sustainable technologies. JECE emphasizes the transition towards a carbon-neutral circular economy and a self-sufficient bio-based economy. Topics covered include soil, water, wastewater, and air decontamination; pollution monitoring, prevention, and control; advanced analytics, sensors, impact and risk assessment methodologies in environmental chemical engineering; resource recovery (water, nutrients, materials, energy); industrial ecology; valorization of waste streams; waste management (including e-waste); climate-water-energy-food nexus; novel materials for environmental, chemical, and energy applications; sustainability and environmental safety; water digitalization, water data science, and machine learning; process integration and intensification; recent developments in green chemistry for synthesis, catalysis, and energy; and original research on contaminants of emerging concern, persistent chemicals, and priority substances, including microplastics, nanoplastics, nanomaterials, micropollutants, antimicrobial resistance genes, and emerging pathogens (viruses, bacteria, parasites) of environmental significance.
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