In-situ formation of γ-TiAl based alloy coatings on a titanium alloy by tungsten inert gas cladding

IF 4.8 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Intermetallics Pub Date : 2025-02-27 DOI:10.1016/j.intermet.2025.108715
Donglu Mo , Cheng Chen , Haonan Zhong , Jian Wang
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Abstract

The γ-TiAl based alloy coatings were synthesized on the Ti-5Al alloy substrates through in-situ surface alloying using the tungsten inert gas (TIG) cladding method. The effects of welding parameters on the microstructure, phase composition and microhardness of the coatings were investigated. The temperature gradient and cooling rate distributions during the melting-solidification process were calculated by means of a numerical simulation method. The results demonstrated that a higher welding current resulted in a narrower and deeper welding pool, while an appropriate increase in welding speed led to a shallower and wider one. A continuous cladding layer without microdefects was obtained at the welding current of 80 A and the welding speed of 200 mm/min. The layer contained about 47.62 at.% Al and was composed of γ-TiAl and α2-Ti3Al phases. The crystallizing morphologies in the welding pool transitioned from planar grains at the bottom to dendrites growing from the bottom to the center, and finally to dendrites aligned with the welding direction at the top. The phase transition of the dendrites proceeded as L→α→γ+α2, and the interdendritic constituents evolved along L→α→γ, ultimately forming a microstructure of massive γ distributed between the α2/γ lamellar colonies. The microhardness of the cladding layer was above 350 HV0.1. The as-synthesized coating had the potential to improve surface properties of the titanium alloy.

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钨惰性气体包覆在钛合金表面原位形成γ-TiAl基合金涂层
采用钨惰性气体(TIG)包覆法,在Ti-5Al基体上原位合金化制备了γ-TiAl基合金涂层。研究了焊接参数对镀层显微组织、相组成和显微硬度的影响。采用数值模拟方法计算了熔融凝固过程中的温度梯度和冷却速率分布。结果表明:焊接电流越大,熔池越窄,熔池越深;焊接速度适当提高,熔池越浅,熔池越宽。在焊接电流为80 A、焊接速度为200 mm/min的条件下,获得了无微缺陷的连续熔覆层。该层含有约47.62个at。由γ-TiAl相和α2-Ti3Al相组成。焊接熔池的结晶形态从底部的平面晶粒到底部向中心生长的枝晶,最后到顶部与焊接方向对齐的枝晶。枝晶的相变顺序为L→α→γ+α2,枝晶间成分沿L→α→γ演化,最终形成分布在α2/γ片层集落之间的块状γ组织。熔覆层显微硬度在350 HV0.1以上。该涂层具有改善钛合金表面性能的潜力。
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来源期刊
Intermetallics
Intermetallics 工程技术-材料科学:综合
CiteScore
7.80
自引率
9.10%
发文量
291
审稿时长
37 days
期刊介绍: This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys. The journal reports the science and engineering of metallic materials in the following aspects: Theories and experiments which address the relationship between property and structure in all length scales. Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations. Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties. Technological applications resulting from the understanding of property-structure relationship in materials. Novel and cutting-edge results warranting rapid communication. The journal also publishes special issues on selected topics and overviews by invitation only.
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