A. S. Igonin, E. I. Isaeva, R. I. Baichurin, S. V. Makarenko
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引用次数: 0
Abstract
Ligands, (2E)-2-(1-phenylethylidene)hydrazine-1-carboxamide (L1) and (2E)-N-phenyl-2-(1-phenylethylidene)hydrazine-1-carboxamide (L2), were synthesized, as well as cyclometallic palladium(II) complexes [(PdL1)2Cl]Cl and [(PdL2)2Cl]Cl with them. Their composition and structure were proven by 1H, 13C, 1H–13C HMQC, 1H–13C HMBC, 1Н–1Н dqf–COSY and 1H–1H NOESY NMR spectroscopy, mass spectrometry, IR and electron spectroscopy. Catalytic activity of the obtained complexes in the Suzuki–Miyaura C–C cross-coupling reactions was demonstrated.
期刊介绍:
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.