Coalescence and Self-Propelled Dynamics of Micron-Sized Oil Droplets on a Fiber with Wettability Gradient

IF 3.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Industrial & Engineering Chemistry Research Pub Date : 2025-02-27 DOI:10.1021/acs.iecr.4c04031
Zeming Fu, Huagen Wu, Yanling Xiong, Zhongxu Jiang, Wenjian Liu, Rongshan Zhang, Ziwen Xing
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Abstract

This work investigates the coalescence and directional movement of microsized oil droplets on a fiber with a wettability gradient using numerical simulations. The volume of fluid (VOF) method and an improved dynamic contact angle model were employed to examine the effects of the wettability gradient on droplet coalescence and motion. The results indicate that as the wettability gradient increases, the droplet movement velocity accelerates, with a maximum velocity of approximately 0.2 m/s. The peak droplet velocity occurs when the trailing edge crosses the wettability transition, and the larger the contact angle on the high-contact angle side, the higher the velocity. The coalescence and self-propelled motion of micron-sized viscous droplets on fibers with wettability gradient occur in the low-Reynolds number regime. Dimensionless analysis shows that as the droplet-to-fiber diameter ratio increases, the velocity increases, but the rate of increase diminishes. The curvature of the fiber surface restricts droplet spreading, causing the maximum velocity to be 25–30% lower than that on a flat surface. During coalescence, microsized oil droplets release nearly 7–12% of their surface energy.

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具有润湿梯度的纤维上微米级油滴的凝聚与自推进动力学
本文采用数值模拟的方法研究了微油滴在具有润湿性梯度的纤维上的聚结和定向运动。采用流体体积法(VOF)和改进的动态接触角模型,研究了润湿性梯度对液滴聚结和运动的影响。结果表明:随着润湿性梯度的增大,液滴运动速度加快,最大运动速度约为0.2 m/s;液滴速度峰值出现在尾缘经过润湿性过渡时,高接触角侧的接触角越大,液滴速度越高。微米级粘滴在具有润湿性梯度的纤维上的聚结和自走运动发生在低雷诺数区。无量纲分析表明,随着液滴与纤维直径比的增大,速度增大,但增大的速率减小。纤维表面的曲率限制了液滴的扩散,导致最大速度比平坦表面低25-30%。在聚结过程中,微油滴释放了近7-12%的表面能。
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来源期刊
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research 工程技术-工程:化工
CiteScore
7.40
自引率
7.10%
发文量
1467
审稿时长
2.8 months
期刊介绍: ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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