Total internal reflection-driven uniform light field engineering for UV-LED water disinfection: A 12-fold performance enhancement in cylindrical reactors

IF 4.1 3区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Photochemistry and Photobiology A-chemistry Pub Date : 2025-02-21 DOI:10.1016/j.jphotochem.2025.116348
Zekai Hong, Taige Dong, Aixin Luo, Guangda Du, Ying Dong, Chuyu Qing, Guanlang Sun, Yongkuan Li, Bingfeng Fan
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Abstract

Ultraviolet (UV) disinfection technology has become increasingly recognized for its effectiveness in pathogen inactivation. Recent advancements have introduced ultraviolet light emitting diodes (UV-LEDs) as a preferable option to traditional UV sources, offering notable advantages. This study focuses on the optimization of a UV water disinfection reactor by utilizing computational simulation to improve disinfection efficiency. Through the integration of total internal reflection (TIR) lenses with UV-LED light sources, the proposed reactor design achieves a more uniform light distribution, with relative standard deviation (RSD) values below 0.3. By this method, the result demonstrates more than a 12-fold improvement in radiation dose (R dose) delivering over conventional reactor designs. The investigation on the light field uniformity reveals that the light distribution within the reactor chamber varies depending on the structural differences. This outcome facilitates the optimization of reactor design. Simulations with contaminated water further validate the enhanced performance of the optimized reactor in applications, emphasizing the potential of UV-LED technology in advancing water disinfection processes. The comprehensive findings of this study offer valuable insights and guidance for the refinement of UV water disinfection reactor establishment.

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CiteScore
7.90
自引率
7.00%
发文量
580
审稿时长
48 days
期刊介绍: JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds. All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor). The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.
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