{"title":"Heteroepitaxial Growth of Sn δ-Doped β-Ga₂O₃ MOSFETs on c-Plane Sapphire via Nonvacuum Mist-CVD Process","authors":"Hao-Chun Hung;Yin-Chu Hsiao;Ching-Yu Cheng;Chia-Cheng Hsu;Fang-Yu Hsu;Rong-Ming Ko;Han-Yin Liu;Wei-Chou Hsu","doi":"10.1109/TED.2025.3527952","DOIUrl":null,"url":null,"abstract":"The heteroepitaxy process for growing thin films of single crystal <inline-formula> <tex-math>$\\beta $ </tex-math></inline-formula>-phase gallium oxide (<inline-formula> <tex-math>$\\beta $ </tex-math></inline-formula>-Ga2O3) on c-plane sapphire substrates was conducted using nonvacuum process mist-chemical vapor deposition. The Sn delta (<inline-formula> <tex-math>$\\delta $ </tex-math></inline-formula>)-doping technique was employed to improve the doping concentration, output current, and gate controllability. The use of tetramethylammonium hydroxide (TMAH) to treat the surface of <inline-formula> <tex-math>$\\beta $ </tex-math></inline-formula>-Ga2O3 results in improving the surface morphology, which reduces contact resistance between the source/drain electrode and <inline-formula> <tex-math>$\\beta $ </tex-math></inline-formula>-Ga2O3. Experimental results show that the <inline-formula> <tex-math>$\\beta $ </tex-math></inline-formula>-Ga2O3 MOSFET with Sn <inline-formula> <tex-math>$\\delta $ </tex-math></inline-formula>-doped layer exposed for 80 s and treatment with TMAH for 5 min proposed in this work exhibit excellent electrical properties, including <inline-formula> <tex-math>${V}_{\\text {TH}}$ </tex-math></inline-formula> of −7.5 V, <inline-formula> <tex-math>${I}_{\\text {DS},\\max }$ </tex-math></inline-formula> of 3.71 mA/mm, a subthreshold swing (SS) of 313.26 mV/dec, <inline-formula> <tex-math>${R}_{\\text {on},\\text {sp}}$ </tex-math></inline-formula> of <inline-formula> <tex-math>$0.6~\\Omega \\cdot \\text {cm}^{{2}}$ </tex-math></inline-formula>, an<sc>off</small>-state breakdown voltage of 1085 V, and a power figure of merit (PFOM) of 1.96 MW/cm2.","PeriodicalId":13092,"journal":{"name":"IEEE Transactions on Electron Devices","volume":"72 3","pages":"996-1001"},"PeriodicalIF":2.9000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IEEE Transactions on Electron Devices","FirstCategoryId":"5","ListUrlMain":"https://ieeexplore.ieee.org/document/10847639/","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
The heteroepitaxy process for growing thin films of single crystal $\beta $ -phase gallium oxide ($\beta $ -Ga2O3) on c-plane sapphire substrates was conducted using nonvacuum process mist-chemical vapor deposition. The Sn delta ($\delta $ )-doping technique was employed to improve the doping concentration, output current, and gate controllability. The use of tetramethylammonium hydroxide (TMAH) to treat the surface of $\beta $ -Ga2O3 results in improving the surface morphology, which reduces contact resistance between the source/drain electrode and $\beta $ -Ga2O3. Experimental results show that the $\beta $ -Ga2O3 MOSFET with Sn $\delta $ -doped layer exposed for 80 s and treatment with TMAH for 5 min proposed in this work exhibit excellent electrical properties, including ${V}_{\text {TH}}$ of −7.5 V, ${I}_{\text {DS},\max }$ of 3.71 mA/mm, a subthreshold swing (SS) of 313.26 mV/dec, ${R}_{\text {on},\text {sp}}$ of $0.6~\Omega \cdot \text {cm}^{{2}}$ , anoff-state breakdown voltage of 1085 V, and a power figure of merit (PFOM) of 1.96 MW/cm2.
期刊介绍:
IEEE Transactions on Electron Devices publishes original and significant contributions relating to the theory, modeling, design, performance and reliability of electron and ion integrated circuit devices and interconnects, involving insulators, metals, organic materials, micro-plasmas, semiconductors, quantum-effect structures, vacuum devices, and emerging materials with applications in bioelectronics, biomedical electronics, computation, communications, displays, microelectromechanics, imaging, micro-actuators, nanoelectronics, optoelectronics, photovoltaics, power ICs and micro-sensors. Tutorial and review papers on these subjects are also published and occasional special issues appear to present a collection of papers which treat particular areas in more depth and breadth.