Research progress of carbon dots as novel corrosion inhibitors

IF 4.7 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Structure Pub Date : 2025-07-05 Epub Date: 2025-02-27 DOI:10.1016/j.molstruc.2025.141894
Haijie He , Zhenghong Zhang , Chaoqiang Jiang , Chuang He
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Abstract

Corrosion is a global issue, costing the economy more than $2.5 trillion annually and affecting metal structures across various industries. Corrosion inhibitors effectively mitigate metal corrosion and are popular in the field of corrosion protection, due to their efficiency, low cost, and environmentally friendly properties. Carbon dots (CDs), as a new class of carbon nanomaterials, show significant potential as corrosion inhibitors. Currently, various methods have been developed to synthesize efficient CD inhibitors, and the structures of CD inhibitors can be easily regulated by changing the synthetic parameters. More importantly, CDs demonstrate promising inhibition performance in various environments, including acidic solutions, NaCl solutions, CO2-saturated NaCl solutions, microbial-corroded solutions, and alkaline solutions. Moreover, their related inhibition mechanisms are revealed through electrochemical methods, surface characterization, adsorption isotherms, and theoretical calculations. This review comprehensively summarizes the research progress of CDs as novel corrosion inhibitors, containing the synthesis methods of CD inhibitors, their applications in different solutions, and their corrosion inhibition mechanisms. This review would inspire researchers to tap into the full potential of CDs as novel corrosion inhibitors.
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新型缓蚀剂碳点的研究进展
腐蚀是一个全球性问题,每年造成的经济损失超过2.5万亿美元,并影响到各个行业的金属结构。缓蚀剂因其高效、低成本、环保等特点,在金属腐蚀防护领域受到广泛欢迎。碳点(CDs)作为一类新型的碳纳米材料,在缓蚀剂方面具有巨大的潜力。目前,合成高效CD抑制剂的方法多种多样,通过改变合成参数可以很容易地调节CD抑制剂的结构。更重要的是,CDs在酸性溶液、NaCl溶液、co2饱和NaCl溶液、微生物腐蚀溶液和碱性溶液等各种环境中都表现出良好的缓蚀性能。此外,通过电化学方法、表面表征、吸附等温线和理论计算揭示了它们的相关抑制机制。本文综述了新型缓蚀剂CD的研究进展,包括CD缓蚀剂的合成方法、在不同溶液中的应用以及其缓蚀机理。这一综述将激励研究人员充分挖掘CDs作为新型缓蚀剂的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Molecular Structure
Journal of Molecular Structure 化学-物理化学
CiteScore
7.10
自引率
15.80%
发文量
2384
审稿时长
45 days
期刊介绍: The Journal of Molecular Structure is dedicated to the publication of full-length articles and review papers, providing important new structural information on all types of chemical species including: • Stable and unstable molecules in all types of environments (vapour, molecular beam, liquid, solution, liquid crystal, solid state, matrix-isolated, surface-absorbed etc.) • Chemical intermediates • Molecules in excited states • Biological molecules • Polymers. The methods used may include any combination of spectroscopic and non-spectroscopic techniques, for example: • Infrared spectroscopy (mid, far, near) • Raman spectroscopy and non-linear Raman methods (CARS, etc.) • Electronic absorption spectroscopy • Optical rotatory dispersion and circular dichroism • Fluorescence and phosphorescence techniques • Electron spectroscopies (PES, XPS), EXAFS, etc. • Microwave spectroscopy • Electron diffraction • NMR and ESR spectroscopies • Mössbauer spectroscopy • X-ray crystallography • Charge Density Analyses • Computational Studies (supplementing experimental methods) We encourage publications combining theoretical and experimental approaches. The structural insights gained by the studies should be correlated with the properties, activity and/ or reactivity of the molecule under investigation and the relevance of this molecule and its implications should be discussed.
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