Bio-Based Multicompartment Photonic Pigments: Unlocking Non-Iridescent Pure RGB Structural Colors for Versatile Chromatic Engineering

Abstract

Non-iridescent photonic glass pigments of block copolymers show great potential for sustainable structural coloration. However, the ability to create accurate RGB color mixtures for real-world applications is limited by the prevalent use of non-degradable, fossil oil-derived components and the difficulty in achieving pure red hues. This work presents an alternative strategy for achieving more sustainable structural coloration by fabricating composite photonic pigments through controlled self-assembly of water, vegetable oil, and biodegradable bottlebrush block copolymers (BBCPs) in a complex emulsion system. The obtained photonic balls feature unprecedented multicompartment structures characterized by a short-range ordered assembly of water nanodroplets stabilized by the BBCPs, along with oil droplets stabilized by these nanodroplets, which substantially enhances resistance to Ostwald ripening. Furthermore, a new structural model is introduced to eliminate disordered scattering, successfully creating a pure red structural color and overcoming a long-standing limitation in versatile chromatic engineering.