Towards high-temperature fuel cells using sulfonated-phosphonated poly(pentafluorostyrene)†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-03-12 Epub Date: 2025-03-05 DOI:10.1039/d4cc06418f
Theresa Stigler , Sebastian Auffarth , Maximilian Wagner , Andreas Hutzler , Simon Thiele , Jochen Kerres
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Abstract

Herein, we present a hybrid polymer material with phosphonic acid and sulfonic acid moieties on a poly(pentafluorostyrene) backbone utilizing the SNAr Michaelis–Arbuzov and the para-fluoro-thiol reaction. Blending the hybrid material with a benzimidazole polymer yielded a mechanically stable membrane featuring proton conductivities up to three times higher than conventional Nafion N211 at temperatures above 120 °C.

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磺化-膦化聚五氟苯乙烯高温燃料电池研究
在此,我们利用SNAr Michaelis-Arbuzov反应和对氟硫醇反应,在聚五氟苯乙烯骨架上制备了膦酸和磺酸基团的杂化聚合物材料。将这种杂化材料与苯并咪唑聚合物混合,得到了一种机械稳定的膜,在120°C以上的温度下,其质子电导率是传统Nafion N211的三倍。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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