Study on the impact of minor ambient temperature variations on the gas sensing performance of zinc cobaltate semiconductor metal oxide sensor for toluene detection

IF 3.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2025-06-15 Epub Date: 2025-03-05 DOI:10.1016/j.snb.2025.137570
Yudong Li , Zhenyu Yuan , Hongmin Zhu , Boyuan Wang , Hao Wang , Fanli Meng
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Abstract

Gas sensing technology is a critical component for ensuring life and industrial safety. With the prosperity of the Internet of Things, the demand for accurate gas sensing has been steadily increasing. Common fluctuations, including ambient temperature, humidity, and interfering pollutants, can cause nonlinear changes in sensor signals, affecting sensor accuracy and potentially leading to false alarms or missed detections. Despite this, research on the impact of ambient temperature on sensor performance remains limited. This study focuses on the ZnCo2O4 sensor to investigate the effects of minor ambient temperature variations on the gas detection process. Test results indicate that an ambient temperature change impacts the performance of metal oxide gas sensors to varying degrees. The pronounced effect of temperature changes on ZnCo2O4 sensors is attributed to its high sensitivity to temperature variations, its hollow nanocage structure, and the low reactivity of the toluene. Finally, a regression model linking response rate, steady-state resistance, and environmental variables was constructed to analyze the impact of ambient temperature on sensing performance, facilitating the identification of ambient temperature and target gas concentration. This work points out the necessity of testing the effect of weak ambient temperature change on metal oxide gas sensors, which is beneficial to the practical application of chemical resistance gas sensors.
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用于甲苯检测的钴酸锌半导体金属氧化物传感器的气体传感性能受微小环境温度变化影响的研究
气体传感技术是确保生命和工业安全的关键组成部分。随着物联网的蓬勃发展,对精确气体传感的需求稳步增长。常见的波动,包括环境温度、湿度和干扰污染物,会导致传感器信号的非线性变化,影响传感器的精度,并可能导致误报或漏检。尽管如此,关于环境温度对传感器性能影响的研究仍然有限。本研究以ZnCo2O4传感器为研究对象,探讨微小环境温度变化对气体检测过程的影响。试验结果表明,环境温度的变化对金属氧化物气体传感器的性能有不同程度的影响。温度变化对ZnCo2O4传感器的显著影响是由于其对温度变化的高灵敏度,其中空的纳米笼结构以及甲苯的低反应性。最后,构建响应率、稳态电阻和环境变量的回归模型,分析环境温度对传感性能的影响,便于环境温度和目标气体浓度的识别。指出了检测环境温度微弱变化对金属氧化物气体传感器影响的必要性,有利于耐化学腐蚀气体传感器的实际应用。
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来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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