Construction of a foaming agent containing hydroxysulfobetaine and α-olefin sulfonate for clastic reservoirs with high temperature and high salinity

IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Petroleum Science Pub Date : 2025-02-01 Epub Date: 2024-11-24 DOI:10.1016/j.petsci.2024.11.011
Long-Jie Li , Ji-Jiang Ge , Peng-Fei Chen , Peng-Ju Chu
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Abstract

High-temperature and high-salt reservoirs are often accompanied by serious gas channeling in gas flooding, which will greatly affect the effect of gas injection development, so in-situ foaming of temperature-resistant and salt-resistant foaming agents is commonly used to control gas channeling. The feasibility of the compound system of dodecyl hydroxyl sulfobetaine (HSB12) and α-olefin sulfonate (AOS) as foaming agent for sandstone reservoir was studied at 130 °C and 22 × 104 mg/L. The results showed that the foaming agent (HSB12 and AOS were compounded in a 6:1 mass ratio, in this article, this foaming agent is simply referred to as SA61) had good solubility in 22 × 104 mg/L simulated formation water. Besides, the foaming volume of SA61 and HSB12 was similar, but the foam decay half-life of SA61 was 10–25 times higher than that of HSB12. The foaming performance of SA61 on the surface of quartz sand remained above 90% of that before adsorption. The strong interaction between HSB12 and AOS in the compound system SA61 was demonstrated by surface rheological measurements and NMR studies of surfactants. The results of core flow test showed that SA61 had better mobility control ability than HSB12 under the same surfactant concentration. In addition, SA61 showed a selective mobility reduction in 2005.30 and 632.00 mD cores. The above research results can guide the selection and application of foaming agent in clastic reservoir.
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高温高矿化度碎屑储层羟基磺基甜菜碱- α-烯烃磺酸盐发泡剂的构建
高温高盐储层在气驱过程中往往伴有严重的气窜现象,这将极大地影响注气开发效果,因此通常采用耐温耐盐发泡剂原位发泡控制气窜。在130℃、22 × 104 mg/L条件下,研究了十二烷基羟基磺基甜菜碱(HSB12)与α-烯烃磺酸盐(AOS)复合体系作为砂岩储层发泡剂的可行性。结果表明,发泡剂HSB12与AOS以6:1的质量比复配,本文中该发泡剂简称SA61,在22 × 104 mg/L模拟地层水中具有良好的溶解度。此外,SA61和HSB12的泡沫体积相似,但SA61的泡沫衰变半衰期比HSB12高10-25倍。SA61在石英砂表面的发泡性能保持在吸附前的90%以上。表面活性剂的表面流变学测量和核磁共振研究证实了HSB12和AOS在SA61化合物体系中的强相互作用。岩心流动试验结果表明,在相同表面活性剂浓度下,SA61比HSB12具有更好的流动性控制能力。此外,SA61在2005.30和632.00 mD岩心中表现出选择性迁移率降低。上述研究结果可指导碎屑储层发泡剂的选择和应用。
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来源期刊
Petroleum Science
Petroleum Science 地学-地球化学与地球物理
CiteScore
7.70
自引率
16.10%
发文量
311
审稿时长
63 days
期刊介绍: Petroleum Science is the only English journal in China on petroleum science and technology that is intended for professionals engaged in petroleum science research and technical applications all over the world, as well as the managerial personnel of oil companies. It covers petroleum geology, petroleum geophysics, petroleum engineering, petrochemistry & chemical engineering, petroleum mechanics, and economic management. It aims to introduce the latest results in oil industry research in China, promote cooperation in petroleum science research between China and the rest of the world, and build a bridge for scientific communication between China and the world.
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