首页 > 最新文献

Petroleum Science最新文献

英文 中文
Performance evaluation of multilateral horizontal wells on flow characteristics and recovery efficiency based on coupled model 基于耦合模型的分支水平井流动特性及采收率动态评价
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-10-30 DOI: 10.1016/j.petsci.2025.10.025
Chun-Xue Cui , Xiao-Long Chai , Yue-Wu Liu , Zhi-Jun Zhou , Guo-Qing Zhang , Leng Tian
The multi-branch horizontal wells can improve the reservoir dynamic flow profile, restrain water coning, enhance production and recovery efficiency due to large drainage area and low cost, and it is significant importance for academic research and industrial applications. However, the effects of branches interference and wellbore variable mass flow on transient dynamics of water breakthrough, production characteristics and recovery efficiency have long been ignored. To dynamically simulate and evaluate the fluid flow behavior of multilateral horizontal wells, first, the branches interference and coupled relationship between reservoir fluid seepage and wellbore variable mass flow has been investigated in this paper, a coupled model for predicting multilateral horizontal wells dynamic production and water breakthrough time is proposed with arbitrary three-dimensional spatial distribution. Subsequently, the model is validated by comparing the production and breakthrough time between actual production data and simulated software. Last, the performance characteristics including inflow dynamics, production, wellbore pressure drop and water breakthrough dynamic distribution are analyzed. The results indicate that the unstable flow time is shorten and it is about 0.6 h, and the wellbore inflow profile represents a characteristic of “low in the middle and high at both ends” on account of branches interference. The pressure drop of wellbore is mainly affected by friction, and other pressure drop types are acceleration pressure drop, convergence pressure drop and mixed pressure drop in order of influence, respectively. The breakthrough time is prior at junction of main wellbore and branch wellbores, then the bottom water spreads to the middle position of main wellbore and trailing position of each branch wellbore. The branch length has a critical impact on breakthrough time, and the branch numbers also affect it as well as the branch angle. The proposed theoretical model can be used to calculate and predict the production, breakthrough time and recovery efficiency of multilateral horizontal wells, and it supplies strong technical support for further development and enhance oil recovery of bottom water reservoir and actual oil field production.
多分支水平井由于排水面积大,成本低,可以改善储层动态流动剖面,抑制水锥,提高生产采收率,具有重要的学术研究和工业应用价值。然而,分支干涉和井筒变质量流对破水瞬态动力学、生产特性和采收率的影响一直被忽视。为了动态模拟和评价分支水平井的流体流动特性,本文首先研究了分支干涉以及储层流体渗流与井筒变质量流之间的耦合关系,提出了任意三维空间分布的分支水平井动态产量与破水时间的耦合预测模型。随后,通过实际生产数据与模拟软件的生产和突破时间对比,对模型进行了验证。最后,分析了井眼流入动态、产量、井眼压降、井眼破水动态分布等动态特征。结果表明:不稳定流动时间缩短,约为0.6 h,受分支干涉影响,井筒流入剖面呈现“中低、两端高”的特征;影响井筒压降的主要因素是摩擦,其他压降类型的影响程度依次为加速压降、收敛压降和混合压降。底水先在主井与分支井交界处突破,然后向主井中部及分支井尾部扩散。分支长度对突破时间有重要影响,分支数和分支角度对突破时间也有影响。该理论模型可用于计算和预测多边水平井的产量、突破时间和采收率,为进一步开发和提高底水油藏采收率及油田实际生产提供有力的技术支持。
{"title":"Performance evaluation of multilateral horizontal wells on flow characteristics and recovery efficiency based on coupled model","authors":"Chun-Xue Cui ,&nbsp;Xiao-Long Chai ,&nbsp;Yue-Wu Liu ,&nbsp;Zhi-Jun Zhou ,&nbsp;Guo-Qing Zhang ,&nbsp;Leng Tian","doi":"10.1016/j.petsci.2025.10.025","DOIUrl":"10.1016/j.petsci.2025.10.025","url":null,"abstract":"<div><div>The multi-branch horizontal wells can improve the reservoir dynamic flow profile, restrain water coning, enhance production and recovery efficiency due to large drainage area and low cost, and it is significant importance for academic research and industrial applications. However, the effects of branches interference and wellbore variable mass flow on transient dynamics of water breakthrough, production characteristics and recovery efficiency have long been ignored. To dynamically simulate and evaluate the fluid flow behavior of multilateral horizontal wells, first, the branches interference and coupled relationship between reservoir fluid seepage and wellbore variable mass flow has been investigated in this paper, a coupled model for predicting multilateral horizontal wells dynamic production and water breakthrough time is proposed with arbitrary three-dimensional spatial distribution. Subsequently, the model is validated by comparing the production and breakthrough time between actual production data and simulated software. Last, the performance characteristics including inflow dynamics, production, wellbore pressure drop and water breakthrough dynamic distribution are analyzed. The results indicate that the unstable flow time is shorten and it is about 0.6 h, and the wellbore inflow profile represents a characteristic of “low in the middle and high at both ends” on account of branches interference. The pressure drop of wellbore is mainly affected by friction, and other pressure drop types are acceleration pressure drop, convergence pressure drop and mixed pressure drop in order of influence, respectively. The breakthrough time is prior at junction of main wellbore and branch wellbores, then the bottom water spreads to the middle position of main wellbore and trailing position of each branch wellbore. The branch length has a critical impact on breakthrough time, and the branch numbers also affect it as well as the branch angle. The proposed theoretical model can be used to calculate and predict the production, breakthrough time and recovery efficiency of multilateral horizontal wells, and it supplies strong technical support for further development and enhance oil recovery of bottom water reservoir and actual oil field production.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 818-835"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147417837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Competition between viscous and capillary forces triggers diversity of fluid distribution and imbibition modes 粘性力和毛细力之间的竞争引发了流体分布和吸胀模式的多样性
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-10-06 DOI: 10.1016/j.petsci.2025.09.043
Jin-Xin Cao , Yi-Qiang Li , Yu-Ling Zhang , Ya-Qian Zhang , Zhe-Yu Liu , Qi-Hang Li , Xue-Chen Tang , Tao Song
Spontaneous imbibition is the process in which the wetting phase displaces a non-wetting phase under the action of capillary forces. However, variations in interfacial properties, imbibition directions, and fractures result in different imbibition modes, posing challenges to a comprehensive understanding of the process. In this study, microfluidic chips representing matrix and fracture–matrix systems were designed. Imbibition agents with varied interfacial properties were selected to conduct experiments under counter-current and co-current conditions. A flow factor (γ), related to fracture geometry and imbibition direction, was defined and used together with the microscopic capillary number (Camicro) to characterize the imbibition process. Three distinct imbibition modes were observed for different Camicro and γ, clearly separated by γCamicro boundaries. During co-current imbibition, an unusual capillary-driven displacement process was observed, leading to fingering in the fracture–matrix model and leaving a large area of macroscale remaining oil. Smaller Camicro and fracture development will facilitate this process. In addition, various forms of microscale remaining oil, caused by bypass flow snap-off and Saffman–Taylor instability/Rayleigh–Taylor instability, were also observed across different imbibition processes. This study elucidates the imbibition mechanisms under the combined influence of capillary and viscous forces, providing deeper insights into the imbibition process in porous media.
自发吸胀是指在毛细力的作用下,湿相取代非湿相的过程。然而,界面性质、吸胀方向和裂缝的变化导致了不同的吸胀模式,这给全面理解这一过程带来了挑战。本研究设计了代表基质和裂缝基质系统的微流控芯片。选取不同界面性能的渗吸剂,在逆流和共流条件下进行了渗吸实验。定义了与裂缝几何形状和渗吸方向相关的流量因子(γ),并将其与微观毛细管数(Ca micro)一起用于表征渗吸过程。对不同的Ca微吸和γ微吸,观察到三种不同的吸吸模式,被γ - Ca微边界明显分开。在共流渗吸过程中,观察到一个不寻常的毛细管驱替过程,导致裂缝基质模型手指化,并留下大面积的宏观剩余油。较小的Ca微晶和裂缝发育将促进这一过程。此外,在不同的渗吸过程中,还观察到由旁通流断裂和Saffman-Taylor不稳定性/ Rayleigh-Taylor不稳定性引起的各种形式的微尺度剩余油。本研究阐明了毛细力和粘滞力共同作用下的吸胀机理,对多孔介质的吸胀过程有了更深入的认识。
{"title":"Competition between viscous and capillary forces triggers diversity of fluid distribution and imbibition modes","authors":"Jin-Xin Cao ,&nbsp;Yi-Qiang Li ,&nbsp;Yu-Ling Zhang ,&nbsp;Ya-Qian Zhang ,&nbsp;Zhe-Yu Liu ,&nbsp;Qi-Hang Li ,&nbsp;Xue-Chen Tang ,&nbsp;Tao Song","doi":"10.1016/j.petsci.2025.09.043","DOIUrl":"10.1016/j.petsci.2025.09.043","url":null,"abstract":"<div><div>Spontaneous imbibition is the process in which the wetting phase displaces a non-wetting phase under the action of capillary forces. However, variations in interfacial properties, imbibition directions, and fractures result in different imbibition modes, posing challenges to a comprehensive understanding of the process. In this study, microfluidic chips representing matrix and fracture–matrix systems were designed. Imbibition agents with varied interfacial properties were selected to conduct experiments under counter-current and co-current conditions. A flow factor (<em>γ</em>), related to fracture geometry and imbibition direction, was defined and used together with the microscopic capillary number (<em>Ca</em><sub>micro</sub>) to characterize the imbibition process. Three distinct imbibition modes were observed for different <em>Ca</em><sub>micro</sub> and <em>γ</em>, clearly separated by <em>γ</em>–<em>Ca</em><sub>micro</sub> boundaries. During co-current imbibition, an unusual capillary-driven displacement process was observed, leading to fingering in the fracture–matrix model and leaving a large area of macroscale remaining oil. Smaller <em>Ca</em><sub>micro</sub> and fracture development will facilitate this process. In addition, various forms of microscale remaining oil, caused by bypass flow snap-off and Saffman–Taylor instability/Rayleigh–Taylor instability, were also observed across different imbibition processes. This study elucidates the imbibition mechanisms under the combined influence of capillary and viscous forces, providing deeper insights into the imbibition process in porous media.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 928-938"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stability mechanism and steady-state flow characteristics of oil-resistant foam in high-salinity reservoirs 高矿化度油藏耐油泡沫稳定机理及稳态流动特征
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-10 DOI: 10.1016/j.petsci.2025.11.014
Lin Sun , Jia-Qi Yin , Hong-Ying Sun , Yan-Ping Wu , Wan-Fen Pu , Bing Wei
High salinity and high oil content present major challenges to the effectiveness of foam in enhanced oil recovery (EOR). This study introduces RCS, a novel oil-resistant foam system designed for reservoirs with salinity levels reaching 2.1 × 105 mg/L. RCS forms stable foams at oil–water ratios up to 60% and is effective across a wide crude oil viscosity range (10.8–7890 mPa·s). We investigated the film properties of oil-containing foam and the co-permeation behavior of the crude oil–N2–foam system to elucidate the mechanisms underlying foam stability and steady-state flow. RCS emulsified high-viscosity crude oil into stable, large droplets that accumulated within the plateau borders, reducing drainage. Even at concentrations as low as 0.01 wt%, RCS formed stable pseudoemulsion films that prevented intrusion into the gas–water interface, allowing the foam half-life to be mainly controlled by the dilatational viscoelasticity of the interface. With increasing oil–water ratios, both drainage resistance and dilatational modulus increased, extending the drainage and foam half-lives. Coreflood experiments showed that co-injection of RCS with N2 and crude oil produced stable foams and in-situ emulsions. At 5% oil fractional flow, the critical foam quality (fg) remained unchanged compared to oil-free conditions, although the maximum apparent viscosity decreased by 29.8%. At 10% oil fractional flow, fg shifted to a lower value, while the apparent viscosity in the low-quality regime increased markedly—exceeding that of the oil-free condition. These findings highlight that while crude oil more strongly impairs foam stability in porous media than in bulk, the formation of in-situ emulsions can partially offset or even enhance mobility control through a synergistic Jamin effect. Therefore, in-situ emulsification should be emphasized in foam applications within oil-containing environments.
高矿化度和高含油量是泡沫提高采收率(EOR)的主要挑战。本文介绍了一种新型耐油泡沫体系RCS,该体系适用于矿化度为2.1 × 105 mg/L的油藏。RCS在油水比高达60%时形成稳定的泡沫,并且在很宽的原油粘度范围(10.8-7890 mPa·s)内有效。研究了含油泡沫的膜性和原油-氮气泡沫体系的共渗透行为,以阐明泡沫稳定性和稳态流动的机制。RCS将高粘度原油乳化成稳定的大液滴,积聚在高原边界内,减少了排水。即使在低至0.01 wt%的浓度下,RCS也能形成稳定的伪乳液膜,防止侵入气水界面,使泡沫半衰期主要由界面的膨胀粘弹性控制。随着油水比的增大,泄油阻力和膨胀模量均增大,泄油半衰期和泡沫半衰期延长。岩心驱替实验表明,RCS与N2和原油共注入可产生稳定的泡沫和原位乳状液。在5%油分流量条件下,临界泡沫质量(fg∗)与无油条件相比保持不变,但最大表观粘度下降了29.8%。在10%的油分流量下,fg∗转向较低的值,而低质量状态下的表观粘度显著增加,超过无油状态。这些发现表明,虽然原油比散装原油更严重地损害了多孔介质中的泡沫稳定性,但原位乳状液的形成可以通过协同的Jamin效应部分抵消甚至增强流动性控制。因此,在含油环境中的泡沫应用中,应强调原位乳化。
{"title":"Stability mechanism and steady-state flow characteristics of oil-resistant foam in high-salinity reservoirs","authors":"Lin Sun ,&nbsp;Jia-Qi Yin ,&nbsp;Hong-Ying Sun ,&nbsp;Yan-Ping Wu ,&nbsp;Wan-Fen Pu ,&nbsp;Bing Wei","doi":"10.1016/j.petsci.2025.11.014","DOIUrl":"10.1016/j.petsci.2025.11.014","url":null,"abstract":"<div><div>High salinity and high oil content present major challenges to the effectiveness of foam in enhanced oil recovery (EOR). This study introduces RCS, a novel oil-resistant foam system designed for reservoirs with salinity levels reaching 2.1 × 10<sup>5</sup> mg/L. RCS forms stable foams at oil–water ratios up to 60% and is effective across a wide crude oil viscosity range (10.8–7890 mPa·s). We investigated the film properties of oil-containing foam and the co-permeation behavior of the crude oil–N<sub>2</sub>–foam system to elucidate the mechanisms underlying foam stability and steady-state flow. RCS emulsified high-viscosity crude oil into stable, large droplets that accumulated within the plateau borders, reducing drainage. Even at concentrations as low as 0.01 wt%, RCS formed stable pseudoemulsion films that prevented intrusion into the gas–water interface, allowing the foam half-life to be mainly controlled by the dilatational viscoelasticity of the interface. With increasing oil–water ratios, both drainage resistance and dilatational modulus increased, extending the drainage and foam half-lives. Coreflood experiments showed that co-injection of RCS with N<sub>2</sub> and crude oil produced stable foams and in-situ emulsions. At 5% oil fractional flow, the critical foam quality (<span><math><mrow><msubsup><mi>f</mi><mi>g</mi><mo>∗</mo></msubsup></mrow></math></span>) remained unchanged compared to oil-free conditions, although the maximum apparent viscosity decreased by 29.8%. At 10% oil fractional flow, <span><math><mrow><msubsup><mi>f</mi><mi>g</mi><mo>∗</mo></msubsup></mrow></math></span> shifted to a lower value, while the apparent viscosity in the low-quality regime increased markedly—exceeding that of the oil-free condition. These findings highlight that while crude oil more strongly impairs foam stability in porous media than in bulk, the formation of in-situ emulsions can partially offset or even enhance mobility control through a synergistic Jamin effect. Therefore, in-situ emulsification should be emphasized in foam applications within oil-containing environments.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 913-927"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147417679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Joint geostatistical seismic inversion of elastic and petrophysical properties using stochastic co-simulation models based on parametric copulas 基于参数copula的随机联合模拟模型的弹性和岩石物理性质联合地统计地震反演
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-13 DOI: 10.1016/j.petsci.2025.10.029
Daniel Vázquez-Ramírez , Martín A. Díaz-Viera , Raúl del Valle-García
Seismic properties play a fundamental role in the geological and petrophysical modeling of reservoirs due to their dependence on petrophysical properties. Most existing stochastic seismic inversion methods are based on Gaussian probability distribution functions and assume linear dependence. Examples include sequential Gaussian co-simulation (SGCS) and direct sequential simulation (DSS). In contrast, spatial stochastic co-simulation methods based on Bernstein copulas (BCCS) have recently been developed. These methods do not require a specific distribution type or linear dependence, thereby overcoming the limitations of traditional approaches.
In this context, we propose a novel approach for the joint seismic inversion of elastic and petrophysical properties using parametric copulas within a Bayesian inference framework. A joint probability distribution is constructed using well-scale petrophysical and elastic property data, fitted to parametric copula functions and treated as prior information. The model parameters are then updated a posteriori using petrophysical properties scaled by a moving window averaging method and seismic properties upscaled using the Backus averaging method. The resulting posterior model is used within the inversion process to generate elastic property realizations at the seismic scale.
The inverse problem is solved using a simulated annealing algorithm that minimizes a global objective function combining the root-mean-square (RMS) error between synthetic and observed seismic traces, and the semivariogram error between the simulated and target variogram models. For each elastic realization, a reflectivity series is computed and convolved with a seismic wavelet to generate a synthetic seismic trace. The best-fitting elastic realization is then used to simulate the corresponding petrophysical property using the same joint probability distribution.
The proposed method was applied to a deepwater reservoir case study to estimate total porosity and acoustic impedance at the seismic scale. Results demonstrate that the use of parametric copulas reduces computational cost and execution time while enabling effective integration of nonlinear dependencies. The synthetic traces exhibit RMS errors below 8%, validating the accuracy and robustness of the copula-based inversion framework.
地震性质依赖于岩石物理性质,在储层地质和岩石物理建模中起着至关重要的作用。现有的随机地震反演方法大多基于高斯概率分布函数,并假设线性相关。例子包括序贯高斯联合仿真(SGCS)和直接序贯仿真(DSS)。相比之下,基于Bernstein copula (BCCS)的空间随机联合模拟方法最近得到了发展。这些方法不需要特定的分布类型或线性依赖,从而克服了传统方法的局限性。在这种情况下,我们提出了一种新的方法,用于在贝叶斯推理框架内使用参数copuls进行弹性和岩石物理性质的联合地震反演。利用井尺度岩石物性和弹性数据构造联合概率分布,拟合为参数耦合函数,并作为先验信息处理。然后,使用移动窗口平均方法对岩石物理性质进行缩放,使用Backus平均方法对地震性质进行缩放,对模型参数进行后验更新。所得后验模型在反演过程中用于生成地震尺度上的弹性特性实现。反演问题采用模拟退火算法求解,该算法结合合成地震道与观测地震道之间的均方根误差以及模拟地震道与目标地震道之间的半变异函数误差,最小化全局目标函数。对于每个弹性实现,计算反射率序列并与地震小波卷积以生成合成地震道。然后利用最佳拟合弹性实现,利用相同的联合概率分布模拟相应的岩石物性。将该方法应用于深水储层案例研究,在地震尺度上估计总孔隙度和声阻抗。结果表明,在有效地集成非线性依赖项的同时,参数copula的使用减少了计算成本和执行时间。合成轨迹的均方根误差低于8%,验证了基于copula的反演框架的准确性和鲁棒性。
{"title":"Joint geostatistical seismic inversion of elastic and petrophysical properties using stochastic co-simulation models based on parametric copulas","authors":"Daniel Vázquez-Ramírez ,&nbsp;Martín A. Díaz-Viera ,&nbsp;Raúl del Valle-García","doi":"10.1016/j.petsci.2025.10.029","DOIUrl":"10.1016/j.petsci.2025.10.029","url":null,"abstract":"<div><div>Seismic properties play a fundamental role in the geological and petrophysical modeling of reservoirs due to their dependence on petrophysical properties. Most existing stochastic seismic inversion methods are based on Gaussian probability distribution functions and assume linear dependence. Examples include sequential Gaussian co-simulation (SGCS) and direct sequential simulation (DSS). In contrast, spatial stochastic co-simulation methods based on Bernstein copulas (BCCS) have recently been developed. These methods do not require a specific distribution type or linear dependence, thereby overcoming the limitations of traditional approaches.</div><div>In this context, we propose a novel approach for the joint seismic inversion of elastic and petrophysical properties using parametric copulas within a Bayesian inference framework. A joint probability distribution is constructed using well-scale petrophysical and elastic property data, fitted to parametric copula functions and treated as prior information. The model parameters are then updated <em>a posteriori</em> using petrophysical properties scaled by a moving window averaging method and seismic properties upscaled using the Backus averaging method. The resulting posterior model is used within the inversion process to generate elastic property realizations at the seismic scale.</div><div>The inverse problem is solved using a simulated annealing algorithm that minimizes a global objective function combining the root-mean-square (RMS) error between synthetic and observed seismic traces, and the semivariogram error between the simulated and target variogram models. For each elastic realization, a reflectivity series is computed and convolved with a seismic wavelet to generate a synthetic seismic trace. The best-fitting elastic realization is then used to simulate the corresponding petrophysical property using the same joint probability distribution.</div><div>The proposed method was applied to a deepwater reservoir case study to estimate total porosity and acoustic impedance at the seismic scale. Results demonstrate that the use of parametric copulas reduces computational cost and execution time while enabling effective integration of nonlinear dependencies. The synthetic traces exhibit RMS errors below 8%, validating the accuracy and robustness of the copula-based inversion framework.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 608-625"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147417948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of acrylic-based wellbore strengthening material in water-based drilling fluid to stabilize the fractured formation 丙烯酸基井筒强化材料在水基钻井液中稳定裂缝地层的应用
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-22 DOI: 10.1016/j.petsci.2025.11.037
Kai-He Lv , Juan He , Xian-Bin Huang , Jin-Sheng Sun
Wellbore instability is the main challenge encountered during borehole construction, particularly when employing water-based drilling fluid (WBDF) under complex geological conditions. A novel wellbore strengthening material of acrylic resin enhanced by hydrophobically modified calcium carbonate particles (ARH) is synthesized by emulsion polymerization. Transmission electron microscope and particle size analysis reveal that ARH exhibits a spherical structure with a Z-average diameter of 277.6 nm. The lap shear strength test shows ARH effectively adheres to two rock slices with a stress of 0.4838 MPa. Uniaxial compressive strength experiments of simulated rock cores verify that ARH can greatly enhance the compressive strength of the simulated core column to 7.1567 MPa. The incorporation of ARH significantly enhances the compressive strength of shale cores, with increases of 18.0620 and 18.9147 MPa compared to those immersed in water and base fluid, respectively. Further microporous membrane plugging experiments show that the filtration losses of 2% ARH in 4% base fluid through 0.1, 0.2, and 0.45 μm microporous membranes are 13.5, 13.2, and 27 mL, respectively, demonstrating excellent plugging capabilities for enhancing wellbore stability. This work generates important theoretical foundations and practical recommendations for wellbore strengthening applications utilizing ARH in complex drilling environments.
井筒不稳定性是井眼施工中遇到的主要挑战,特别是在复杂地质条件下使用水基钻井液(WBDF)时。采用乳液聚合的方法合成了疏水改性碳酸钙颗粒(ARH)增强丙烯酸树脂的新型井筒增强材料。透射电镜和粒度分析表明,ARH呈球形结构,Z -平均直径为277.6 nm。搭接抗剪强度试验表明,ARH在应力为0.4838 MPa的两块岩石片上有效粘附。模拟岩心单轴抗压强度试验验证,ARH可显著提高模拟岩心柱抗压强度,达到7.1567 MPa。ARH的掺入显著提高了页岩岩心的抗压强度,与浸泡在水和基液中的岩心相比,ARH的抗压强度分别提高了18.0620和18.9147 MPa。进一步的微孔膜封堵实验表明,2% ARH在4%基液中通过0.1 μm、0.2 μm和0.45 μm微孔膜的滤失分别为13.5、13.2和27 mL,显示出良好的封堵能力,可以提高井筒稳定性。这项工作为在复杂钻井环境中利用ARH加强井筒提供了重要的理论基础和实践建议。
{"title":"Application of acrylic-based wellbore strengthening material in water-based drilling fluid to stabilize the fractured formation","authors":"Kai-He Lv ,&nbsp;Juan He ,&nbsp;Xian-Bin Huang ,&nbsp;Jin-Sheng Sun","doi":"10.1016/j.petsci.2025.11.037","DOIUrl":"10.1016/j.petsci.2025.11.037","url":null,"abstract":"<div><div>Wellbore instability is the main challenge encountered during borehole construction, particularly when employing water-based drilling fluid (WBDF) under complex geological conditions. A novel wellbore strengthening material of acrylic resin enhanced by hydrophobically modified calcium carbonate particles (ARH) is synthesized by emulsion polymerization. Transmission electron microscope and particle size analysis reveal that ARH exhibits a spherical structure with a <em>Z</em>-average diameter of 277.6 nm. The lap shear strength test shows ARH effectively adheres to two rock slices with a stress of 0.4838 MPa. Uniaxial compressive strength experiments of simulated rock cores verify that ARH can greatly enhance the compressive strength of the simulated core column to 7.1567 MPa. The incorporation of ARH significantly enhances the compressive strength of shale cores, with increases of 18.0620 and 18.9147 MPa compared to those immersed in water and base fluid, respectively. Further microporous membrane plugging experiments show that the filtration losses of 2% ARH in 4% base fluid through 0.1, 0.2, and 0.45 μm microporous membranes are 13.5, 13.2, and 27 mL, respectively, demonstrating excellent plugging capabilities for enhancing wellbore stability. This work generates important theoretical foundations and practical recommendations for wellbore strengthening applications utilizing ARH in complex drilling environments.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 730-741"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Genesis of Late Carboniferous volcanic rocks in the Kebai Fault Zone, Western Junggar, Xinjiang: Constraints from zircon U-Pb age, whole rock geochemistry, and Sr-Nd-Pb isotopes 新疆西准噶尔克白断裂带晚石炭世火山岩成因:锆石U-Pb年龄、全岩地球化学和Sr-Nd-Pb同位素约束
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-04 DOI: 10.1016/j.petsci.2025.10.030
Wei Wang , Chuan-Yi Tang , Zong-Quan Yao , Yan Gao , Feng-Bin Han , Zong-Rui Xie , Jian Chen , Yuan-Feng Yang , Ya-Fang Zhang
The Late Paleozoic tectonic evolution of the Junggar Basin played a critical role in the formation of its oil and gas resources; however, as most of the basin is covered by desert, the evolutionary process remains controversial. In this study, we present a comprehensive analysis of the rock associations, petrography, ages, and systematic elemental and isotopic compositions of Carboniferous volcanic rocks obtained from drilling holes along the western margin of the basin, aiming to better constrain the late Paleozoic tectonic evolution of this region. Two zircon samples, from tuff and andesite layers, yielded concordant ages of 316.8 ± 1.7 and 321.7 ± 1.8 Ma, respectively, indicating intense volcanic eruptions during the Late Carboniferous. The analyzed volcanic rocks exhibited sodic calc-alkaline affinities, with SiO2 content ranging from 53.46 to 61.57 wt%, TiO2 content from 0.75 to 1.20 wt%, and a significantly higher Na2O content than that of K2O. In terms of trace elements, they showed variable enrichment in light rare earth elements ((La/Yb)N = 2.72 to 7.89) and large ion lithophile elements such as Ba, Th, U, and Sr. Low Cr (0.67–65.72) and Ni (0.86–34.90) contents, together with significant negative Eu anomalies (δEu = 0.17 to 0.35), suggest variable fractionation of the primitive magma prior to eruption. All these features, combined with prominent Nb-Ta depletions in PM-normalized incompatible element spider diagrams, unambiguously indicate their genetic relationship with a subduction environment. However, the volcanic rocks showed low initial (87Sr/86Sr)i values (0.7039–0.7057) and positive εNd(t) values (7.5–8.0). Moreover, the combined (208Pb/204Pb)i ranged from 37.7295 to 37.7851, (207Pb/204Pb)i ranged from 15.4935 to 15.5037, and (206Pb/204Pb)i ranged from 17.8910 to 17.9254, indicating that their primitive magma originated from an extremely depleted mantle source with crustal contamination. Integrating this study with regional geology, we propose that the volcanic rocks in the Kebai Fault Zone were most likely formed in a back-arc basin setting induced by ridge subduction.
准噶尔盆地晚古生代构造演化对其油气资源的形成起着关键作用;然而,由于大部分盆地被沙漠覆盖,进化过程仍然存在争议。本文对盆地西缘石炭系火山岩的岩石组合、岩石学、年龄、系统元素和同位素组成进行了综合分析,以期更好地约束该地区晚古生代的构造演化。凝灰岩和安山岩的锆石年龄分别为316.8±1.7 Ma和321.7±1.8 Ma,表明晚石炭世有强烈的火山喷发。分析的火山岩具有钠钙碱性亲和性,SiO2含量在53.46 ~ 61.57 wt%之间,TiO2含量在0.75 ~ 1.20 wt%之间,Na2O含量明显高于K2O。微量元素方面,轻稀土元素(La/Yb)N = 2.72 ~ 7.89)和大离子亲石元素(Ba、Th、U、sr)富集变化较大,低Cr(0.67 ~ 65.72)、Ni(0.86 ~ 34.90)含量显著,且Eu呈显著负异常(δEu = 0.17 ~ 0.35),表明原始岩浆在喷发前分选变化较大。所有这些特征,结合pm标准化不相容元素蜘蛛图中显著的Nb-Ta消耗,明确表明它们与俯冲环境的成因关系。而火山岩具有较低的初始(87Sr/86Sr)i值(0.7039 ~ 0.7057)和正的εNd(t)值(7.5 ~ 8.0)。(208Pb/204Pb)i的组合范围为37.7295 ~ 37.7851,(207Pb/204Pb)i的组合范围为15.4935 ~ 15.5037,(206Pb/204Pb)i的组合范围为17.8910 ~ 17.9254,表明它们的原始岩浆来源于极贫的地幔源,并伴有地壳污染。结合区域地质研究,认为克白断裂带火山岩极有可能形成于脊状俯冲诱发的弧后盆地环境。
{"title":"Genesis of Late Carboniferous volcanic rocks in the Kebai Fault Zone, Western Junggar, Xinjiang: Constraints from zircon U-Pb age, whole rock geochemistry, and Sr-Nd-Pb isotopes","authors":"Wei Wang ,&nbsp;Chuan-Yi Tang ,&nbsp;Zong-Quan Yao ,&nbsp;Yan Gao ,&nbsp;Feng-Bin Han ,&nbsp;Zong-Rui Xie ,&nbsp;Jian Chen ,&nbsp;Yuan-Feng Yang ,&nbsp;Ya-Fang Zhang","doi":"10.1016/j.petsci.2025.10.030","DOIUrl":"10.1016/j.petsci.2025.10.030","url":null,"abstract":"<div><div>The Late Paleozoic tectonic evolution of the Junggar Basin played a critical role in the formation of its oil and gas resources; however, as most of the basin is covered by desert, the evolutionary process remains controversial. In this study, we present a comprehensive analysis of the rock associations, petrography, ages, and systematic elemental and isotopic compositions of Carboniferous volcanic rocks obtained from drilling holes along the western margin of the basin, aiming to better constrain the late Paleozoic tectonic evolution of this region. Two zircon samples, from tuff and andesite layers, yielded concordant ages of 316.8 ± 1.7 and 321.7 ± 1.8 Ma, respectively, indicating intense volcanic eruptions during the Late Carboniferous. The analyzed volcanic rocks exhibited sodic calc-alkaline affinities, with SiO<sub>2</sub> content ranging from 53.46 to 61.57 wt%, TiO<sub>2</sub> content from 0.75 to 1.20 wt%, and a significantly higher Na<sub>2</sub>O content than that of K<sub>2</sub>O. In terms of trace elements, they showed variable enrichment in light rare earth elements ((La/Yb)<sub>N</sub> = 2.72 to 7.89) and large ion lithophile elements such as Ba, Th, U, and Sr. Low Cr (0.67–65.72) and Ni (0.86–34.90) contents, together with significant negative Eu anomalies (<em>δ</em>Eu = 0.17 to 0.35), suggest variable fractionation of the primitive magma prior to eruption. All these features, combined with prominent Nb-Ta depletions in PM-normalized incompatible element spider diagrams, unambiguously indicate their genetic relationship with a subduction environment. However, the volcanic rocks showed low initial (<sup>87</sup>Sr/<sup>86</sup>Sr)<sub>i</sub> values (0.7039–0.7057) and positive <em>ε</em><sub>Nd</sub>(<em>t</em>) values (7.5–8.0). Moreover, the combined (<sup>208</sup>Pb/<sup>204</sup>Pb)<sub>i</sub> ranged from 37.7295 to 37.7851, (<sup>207</sup>Pb/<sup>204</sup>Pb)<sub>i</sub> ranged from 15.4935 to 15.5037, and (<sup>206</sup>Pb/<sup>204</sup>Pb)<sub>i</sub> ranged from 17.8910 to 17.9254, indicating that their primitive magma originated from an extremely depleted mantle source with crustal contamination. Integrating this study with regional geology, we propose that the volcanic rocks in the Kebai Fault Zone were most likely formed in a back-arc basin setting induced by ridge subduction.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 712-729"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147418373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel approach to evaluating remaining oil potential using dynamic connectivity and bivariate mapping in large-scale reservoirs 基于动态连通性和二元映射的大型储层剩余油潜力评价新方法
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-12-16 DOI: 10.1016/j.petsci.2025.12.018
Jun-Da Wu, Tao Chang, Yi-Fan He, Quan-Lin Wang, Di Wang
In the development of water flooding reservoirs, enhancing oil recovery often requires implementing measures tailored to the reservoir's specific characteristics. A critical step in this process is evaluating the remaining oil potential, which directly influences the effectiveness of recovery strategies. However, evaluating the remaining oil potential in large reservoirs is challenging due to reservoir heterogeneity and complex well patterns. Existing evaluation methods are often cumbersome and lack intuitiveness. To address these issues, this study proposes a novel method for evaluating remaining oil potential by utilizing reservoir dynamic connectivity and remaining oil abundance. This method draws upon the advantages of the Eikonal equation in accurately describing the pressure wavefront and its propagation speed. By replacing traditional analytical methods with bivariate mapping, this approach effectively visualizes and correlates dynamic and static attributes. On this basis, the reservoir is classified into four regions: uneconomic/awaiting measures, low-efficiency waterflooding, major potential, and primary production. The potential of each region is intuitively analyzed and evaluated, offering clear insights into development status, untapped potential, and optimal strategies for reservoirs within each region. The application of this method to the M oilfield in the Bohai Sea yielded promising results across three distinct scenarios aimed at enhancing recovery: horizontal well water control, injection–production system optimization, and infill horizontal well deployment. These successful outcomes highlight the applicability of this method to complex, large-scale reservoirs and highlight its potential as a valuable tool for guiding recovery strategies in other challenging reservoir environments.
在水驱油藏开发过程中,提高采收率往往需要根据油藏的具体特点实施相应的措施。这一过程中的一个关键步骤是评估剩余油潜力,这直接影响到采收率策略的有效性。然而,由于储层非均质性和井网复杂,评价大型储层剩余油潜力具有挑战性。现有的评价方法往往繁琐且缺乏直观性。为了解决这些问题,本研究提出了一种利用储层动态连通性和剩余油丰度来评价剩余油潜力的新方法。该方法利用了Eikonal方程在准确描述压力波前及其传播速度方面的优点。该方法用二元映射代替传统的分析方法,有效地实现了动态和静态属性的可视化和关联。在此基础上,将储层划分为不经济/待措施区、低效注水区、主要潜力区和初级采油区。对每个区域的潜力进行直观的分析和评价,为每个区域的开发状况、未开发潜力和最佳储层策略提供清晰的见解。将该方法应用于渤海M油田,在水平井控水、注采系统优化和水平井充填部署三种不同的方案中均取得了令人满意的结果,以提高采收率。这些成功的结果表明,该方法适用于复杂的大型油藏,并有潜力成为指导其他具有挑战性的油藏环境中采收率策略的宝贵工具。
{"title":"A novel approach to evaluating remaining oil potential using dynamic connectivity and bivariate mapping in large-scale reservoirs","authors":"Jun-Da Wu,&nbsp;Tao Chang,&nbsp;Yi-Fan He,&nbsp;Quan-Lin Wang,&nbsp;Di Wang","doi":"10.1016/j.petsci.2025.12.018","DOIUrl":"10.1016/j.petsci.2025.12.018","url":null,"abstract":"<div><div>In the development of water flooding reservoirs, enhancing oil recovery often requires implementing measures tailored to the reservoir's specific characteristics. A critical step in this process is evaluating the remaining oil potential, which directly influences the effectiveness of recovery strategies. However, evaluating the remaining oil potential in large reservoirs is challenging due to reservoir heterogeneity and complex well patterns. Existing evaluation methods are often cumbersome and lack intuitiveness. To address these issues, this study proposes a novel method for evaluating remaining oil potential by utilizing reservoir dynamic connectivity and remaining oil abundance. This method draws upon the advantages of the Eikonal equation in accurately describing the pressure wavefront and its propagation speed. By replacing traditional analytical methods with bivariate mapping, this approach effectively visualizes and correlates dynamic and static attributes. On this basis, the reservoir is classified into four regions: uneconomic/awaiting measures, low-efficiency waterflooding, major potential, and primary production. The potential of each region is intuitively analyzed and evaluated, offering clear insights into development status, untapped potential, and optimal strategies for reservoirs within each region. The application of this method to the M oilfield in the Bohai Sea yielded promising results across three distinct scenarios aimed at enhancing recovery: horizontal well water control, injection–production system optimization, and infill horizontal well deployment. These successful outcomes highlight the applicability of this method to complex, large-scale reservoirs and highlight its potential as a valuable tool for guiding recovery strategies in other challenging reservoir environments.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 836-850"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147417839","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seismic simulation for distributed acoustic sensing data using a novel stress and strain-rate elastic wave equation 基于应力应变率弹性波动方程的分布式声传感数据地震模拟
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-09-15 DOI: 10.1016/j.petsci.2025.09.015
Chong Zhao , Ji-Dong Yang , Jian-Ping Huang , Ning Qin , Kun Tian , Fei-Long Yang
Distributed acoustic sensing (DAS) is an advanced seismic acquisition technology with many advantages, such as low cost, wide frequency band, dense spatial sampling, and continuous recording. The straight optical fiber is restricted to single-component data and exhibits the lack of broadside sensitivity. To address the limitations of straight optical fiber and investigate the seismic response of multi-component DAS system, we proposed a novel first-order stress and strain-rate elastic wave equation to simulate the propagation of strain-rate wavefields. Compared to conventional particle-velocity wavefields, the simulations of three numerical examples demonstrate that the proposed equation can correctly generate elastic normal strain-rate wavefields and produce multi-component DAS data. Additionally, the simulations indicate that increasing the gauge length reduces the measurement accuracy of DAS, and a helical-wound optical fiber at a winding angle of 35.3° remains insensitive to S-wave, whereas it can clearly record S-wave at 54.7°. Furthermore, this equation can be directly implemented for multi-component DAS revers time migration (RTM) or FWI, thereby eliminating the need for traditional data conversion.
分布式声传感(DAS)是一种先进的地震采集技术,具有成本低、频带宽、空间采样密集、记录连续等优点。直光纤受限于单组分数据,并且显示出缺乏宽侧灵敏度。为了解决直光纤的局限性,研究多分量DAS系统的地震响应,我们提出了一种新的一阶应力和应变率弹性波动方程来模拟应变率波场的传播。与传统的粒子速度波场相比,三个数值算例的仿真结果表明,所提方程能正确地生成弹性法向应变率波场,并能生成多分量DAS数据。此外,仿真结果表明,增大光纤仪表长度会降低DAS的测量精度,并且螺旋缠绕光纤在35.3°缠绕角时对s波不敏感,而在54.7°缠绕角时可以清晰地记录s波。此外,该方程可直接用于多组分DAS逆时迁移(RTM)或FWI,从而消除了传统数据转换的需要。
{"title":"Seismic simulation for distributed acoustic sensing data using a novel stress and strain-rate elastic wave equation","authors":"Chong Zhao ,&nbsp;Ji-Dong Yang ,&nbsp;Jian-Ping Huang ,&nbsp;Ning Qin ,&nbsp;Kun Tian ,&nbsp;Fei-Long Yang","doi":"10.1016/j.petsci.2025.09.015","DOIUrl":"10.1016/j.petsci.2025.09.015","url":null,"abstract":"<div><div>Distributed acoustic sensing (DAS) is an advanced seismic acquisition technology with many advantages, such as low cost, wide frequency band, dense spatial sampling, and continuous recording. The straight optical fiber is restricted to single-component data and exhibits the lack of broadside sensitivity. To address the limitations of straight optical fiber and investigate the seismic response of multi-component DAS system, we proposed a novel first-order stress and strain-rate elastic wave equation to simulate the propagation of strain-rate wavefields. Compared to conventional particle-velocity wavefields, the simulations of three numerical examples demonstrate that the proposed equation can correctly generate elastic normal strain-rate wavefields and produce multi-component DAS data. Additionally, the simulations indicate that increasing the gauge length reduces the measurement accuracy of DAS, and a helical-wound optical fiber at a winding angle of 35.3° remains insensitive to S-wave, whereas it can clearly record S-wave at 54.7°. Furthermore, this equation can be directly implemented for multi-component DAS revers time migration (RTM) or FWI, thereby eliminating the need for traditional data conversion.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 626-642"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147418372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Long-term sustained release of small molecular surfactants using microcapsules 利用微胶囊长期缓释小分子表面活性剂
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-13 DOI: 10.1016/j.petsci.2025.11.019
Shuang Liu , Ling-Ling Ren , Zheng Wang , Jia-Wei Shi , Chen-Guang Wang , Jia-Hui Guo , Lu Zhang , Hao-Ran Cheng , Li-Yuan Zhang
The controlled manipulation of surfactant concentration is essential for optimizing performance in numerous industrial applications, such as enhanced oil recovery in oil industry. However, encapsulating surfactants has proven challenging due to their propensity to localize at interfaces. In this study, we use microfluidic technology to fabricate poly (ethylene glycol) diacrylate-based microcapsules for encapsulating small molecular cargoes through finely tuning the relationships among the interfacial tensions of inner, middle and outer phases. These microcapsules show excellent retention by regulating the shell thickness and monomer content, releasing less than 47.2% over 49 d at 20 °C. Upon oil contact, surfactant release is indicated by a contact angle decrease of 7.2° at 20 °C and 21.8° at 50 °C within 48 h. The releases of nonionic Tween 80 and zwitterionic Betaine 1 calculated via surface tension in saline solutions at 80 °C are reduced to as low as 8.2% within 48 h and 1.1% within 8 h. The pressure-induced release reaches 22.7% within 24 h under 15 MPa, significantly exceeding the impacts of temperature and salinity. Notably, even microcapsules with reduced eccentricity still demonstrate sustained-release behavior. Mechanical and degradation tests show that the sustained release is driven by the increase in pore size of the shell due to its gradual degradation. This tunable system offers a versatile platform for encapsulating and controlling the release of surfactants or other sensitive agents, ideal for harsh environmental applications requiring sustained functionality.
在许多工业应用中,表面活性剂浓度的控制对于优化性能至关重要,例如提高石油工业的采收率。然而,由于表面活性剂倾向于在界面处定位,因此封装表面活性剂具有挑战性。在本研究中,我们利用微流控技术,通过微调内、中、外相之间的界面张力关系,制备了以聚乙二醇二丙烯酸酯为基础的微胶囊,用于封装小分子货物。这些微胶囊通过调节壳体厚度和单体含量表现出良好的保留性能,在20°C条件下,49 d内释放量低于47.2%。油接触时,表面活性剂释放由接触角表示减少7.2°20°C和21.8°50°C在48 h。80年发布的非离子渐变和两性离子甜菜碱1通过在盐溶液表面张力计算80°C减少至8.2%在48 h内和1.1% 8 h。pressure-induced 15 MPa下24小时内释放达到22.7%,大大超过温度和盐度的影响。值得注意的是,即使偏心率降低的微胶囊仍然表现出持续释放的行为。力学试验和降解试验表明,缓释是由逐渐降解导致的壳孔尺寸增大所驱动的。这种可调系统为封装和控制表面活性剂或其他敏感剂的释放提供了一个多功能平台,非常适合需要持续功能的恶劣环境应用。
{"title":"Long-term sustained release of small molecular surfactants using microcapsules","authors":"Shuang Liu ,&nbsp;Ling-Ling Ren ,&nbsp;Zheng Wang ,&nbsp;Jia-Wei Shi ,&nbsp;Chen-Guang Wang ,&nbsp;Jia-Hui Guo ,&nbsp;Lu Zhang ,&nbsp;Hao-Ran Cheng ,&nbsp;Li-Yuan Zhang","doi":"10.1016/j.petsci.2025.11.019","DOIUrl":"10.1016/j.petsci.2025.11.019","url":null,"abstract":"<div><div>The controlled manipulation of surfactant concentration is essential for optimizing performance in numerous industrial applications, such as enhanced oil recovery in oil industry. However, encapsulating surfactants has proven challenging due to their propensity to localize at interfaces. In this study, we use microfluidic technology to fabricate poly (ethylene glycol) diacrylate-based microcapsules for encapsulating small molecular cargoes through finely tuning the relationships among the interfacial tensions of inner, middle and outer phases. These microcapsules show excellent retention by regulating the shell thickness and monomer content, releasing less than 47.2% over 49 d at 20 °C. Upon oil contact, surfactant release is indicated by a contact angle decrease of 7.2° at 20 °C and 21.8° at 50 °C within 48 h. The releases of nonionic Tween 80 and zwitterionic Betaine 1 calculated via surface tension in saline solutions at 80 °C are reduced to as low as 8.2% within 48 h and 1.1% within 8 h. The pressure-induced release reaches 22.7% within 24 h under 15 MPa, significantly exceeding the impacts of temperature and salinity. Notably, even microcapsules with reduced eccentricity still demonstrate sustained-release behavior. Mechanical and degradation tests show that the sustained release is driven by the increase in pore size of the shell due to its gradual degradation. This tunable system offers a versatile platform for encapsulating and controlling the release of surfactants or other sensitive agents, ideal for harsh environmental applications requiring sustained functionality.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 954-965"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147330855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the effect of nanoemulsion on the EOR in low-permeability, highly waxy oil reservoirs based on NMR displacement experiments 基于核磁共振驱替实验研究纳米乳液对低渗透高含油油藏提高采收率的影响
IF 6.1 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-02-01 Epub Date: 2025-11-13 DOI: 10.1016/j.petsci.2025.11.013
Rui-Jie Fei , Ming-Hui Li , Shuai Yuan , Chen Cao , Fu-Jian Zhou , Er-Dong Yao , Hao Bai , Diu-Wei Ding
Wax precipitation damage caused by cold water injection or temperature reduction is very commonly seen in the development of waxy crude oil reservoirs. Various methods for eliminating wax precipitation damage have been studied by many scholars, such as injecting hot water, artificial fracture, and using chemical dewaxing agents. However, the effects of nanoemulsion on wax crystals and enhanced oil recovery (EOR) have not yet been systematically studied. This study used core displacement system based on nuclear magnetic resonance (NMR) to investigate the effect of nanoemulsion on the EOR in low-permeability, waxy oil reservoirs. Some influencing factors such as injection water temperatures, core permeability, fractured/unfractured core, and nanoemulsion concentration conditions have been investigated. Meanwhile, the wax crystal morphology and quantity have been studied before and after using nanoemulsion using a polarizing microscope. The main conclusions are as follows: (1) After injecting 60 °C hot water, the recovery can be increased from 19.36% to 32.82%, which can alleviate wax deposition damage to a certain extent. (2) Enhancing core permeability or using fractured cores can increase the flow capacity of displacement fluid within the core and enhance waxy crude oil recovery. The EOR after improving core permeability is 10.22%, while the EOR of the fractured core is 26.24%. (3) Nanoemulsions can dissolve wax crystals in waxy crude oil and inhibit their formation to achieve EOR. The crude oil recovery at nanoemulsion concentrations of 0.1, 0.5, and 1.0 wt% were 34.84%, 38.24%, and 42.85%, respectively. (4) The use of nanoemulsion can reduce the number, area ratio, and fractal dimension of wax crystals, thereby mitigating wax deposition damage. Using a 1 wt% of nanoemulsion, the area ratio of wax crystals decreased from 47.25% to 16.67%, and the number of wax crystals decreased from 1309 to 496.
注冷水或降温引起的蜡沉淀损害是含蜡原油油藏开发中常见的现象。许多学者研究了各种消除蜡沉淀损害的方法,如注入热水、人工压裂、使用化学脱蜡剂等。然而,纳米乳液对蜡晶体和提高采收率的影响尚未得到系统的研究。采用基于核磁共振(NMR)的岩心驱替系统,研究了纳米乳液对低渗透含蜡油藏提高采收率的影响。研究了注入水温度、岩心渗透率、裂缝/未裂缝岩心以及纳米乳浓度条件等影响因素。同时,利用偏光显微镜对纳米乳前后的蜡晶形貌和数量进行了研究。主要结论如下:(1)注入60℃热水后,回收率可由19.36%提高到32.82%,可在一定程度上缓解蜡沉积损伤。(2)提高岩心渗透率或采用压裂岩心可增加岩心内驱替流体的流动能力,提高含蜡原油采收率。提高岩心渗透率后的提高采收率为10.22%,而裂缝岩心的提高采收率为26.24%。(3)纳米乳液可以溶解含蜡原油中的蜡晶,抑制蜡晶的形成,达到提高采收率的目的。纳米乳浓度为0.1、0.5和1.0 wt%时,原油采收率分别为34.84%、38.24%和42.85%。(4)纳米乳液的使用可以减少蜡晶体的数量、面积比和分形维数,从而减轻蜡沉积损伤。当纳米乳液质量分数为1 wt%时,蜡晶的面积比从47.25%下降到16.67%,蜡晶的数量从1309个下降到496个。
{"title":"Study of the effect of nanoemulsion on the EOR in low-permeability, highly waxy oil reservoirs based on NMR displacement experiments","authors":"Rui-Jie Fei ,&nbsp;Ming-Hui Li ,&nbsp;Shuai Yuan ,&nbsp;Chen Cao ,&nbsp;Fu-Jian Zhou ,&nbsp;Er-Dong Yao ,&nbsp;Hao Bai ,&nbsp;Diu-Wei Ding","doi":"10.1016/j.petsci.2025.11.013","DOIUrl":"10.1016/j.petsci.2025.11.013","url":null,"abstract":"<div><div>Wax precipitation damage caused by cold water injection or temperature reduction is very commonly seen in the development of waxy crude oil reservoirs. Various methods for eliminating wax precipitation damage have been studied by many scholars, such as injecting hot water, artificial fracture, and using chemical dewaxing agents. However, the effects of nanoemulsion on wax crystals and enhanced oil recovery (EOR) have not yet been systematically studied. This study used core displacement system based on nuclear magnetic resonance (NMR) to investigate the effect of nanoemulsion on the EOR in low-permeability, waxy oil reservoirs. Some influencing factors such as injection water temperatures, core permeability, fractured/unfractured core, and nanoemulsion concentration conditions have been investigated. Meanwhile, the wax crystal morphology and quantity have been studied before and after using nanoemulsion using a polarizing microscope. The main conclusions are as follows: (1) After injecting 60 °C hot water, the recovery can be increased from 19.36% to 32.82%, which can alleviate wax deposition damage to a certain extent. (2) Enhancing core permeability or using fractured cores can increase the flow capacity of displacement fluid within the core and enhance waxy crude oil recovery. The EOR after improving core permeability is 10.22%, while the EOR of the fractured core is 26.24%. (3) Nanoemulsions can dissolve wax crystals in waxy crude oil and inhibit their formation to achieve EOR. The crude oil recovery at nanoemulsion concentrations of 0.1, 0.5, and 1.0 wt% were 34.84%, 38.24%, and 42.85%, respectively. (4) The use of nanoemulsion can reduce the number, area ratio, and fractal dimension of wax crystals, thereby mitigating wax deposition damage. Using a 1 wt% of nanoemulsion, the area ratio of wax crystals decreased from 47.25% to 16.67%, and the number of wax crystals decreased from 1309 to 496.</div></div>","PeriodicalId":19938,"journal":{"name":"Petroleum Science","volume":"23 2","pages":"Pages 897-912"},"PeriodicalIF":6.1,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147417678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Petroleum Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1