Multifunctional silver-doped strontium hexaferrite nanoparticles: Magnetic, optical, photocatalytic, and antimicrobial properties

Chemistry of Inorganic Materials Pub Date : 2025-04-01 Epub Date: 2025-02-24 DOI:10.1016/j.cinorg.2025.100098
Koustav Ganguly , Priyambada Mahapatra , Chirasmayee Mohanty , Chaitali Das , Alaka Samal , Ranjan Kumar Sahu , Nigamananda Das
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Abstract

The magnetic Strontium hexaferrite nanoparticles (SrFe12O19) decorated with Silver (Ag) catalyst were designed to degrade Rhodamine B and Congo Red dyes, as well as to explore their antibacterial activity against Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli. These nanoparticles were synthesized using a microwave-assisted combustion method, resulting in a series of Ag-decorated SrFe12O19 Nanoparticles. Characterization through PXRD, UV–visible DRS, Raman spectroscopy, and FE-SEM/TEM confirmed the formation of M-type hexagonal SrFe12O19 with uniformly distributed Ag NPs. The addition of Ag influenced the magnetic and optical properties of the SrFe12O19, with a slight decrease in optical band gaps and a reduction in saturation magnetization from 84 to 71 emu/g as Ag content increased to 10 ​wt%. Although the Ag decoration did not enhance the photocatalytic activity of SrFe12O19 for dye degradation under visible light, the photocatalysts were magnetically separable and reusable without significant efficiency loss. Moreover, the heterojunction exhibited a disinfection capacity that was five times quicker than the individual catalysts, highlighting its potential for environmental and antibacterial applications.

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多功能掺杂银的六铁铁氧体锶纳米颗粒:磁性、光学、光催化和抗菌性能
采用银(Ag)催化剂修饰磁性六铁酸锶纳米粒子(SrFe12O19),对罗丹明B和刚果红染料进行了降解,并对革兰氏阳性金黄色葡萄球菌和革兰氏阴性大肠杆菌进行了抑菌活性研究。采用微波辅助燃烧法合成了这些纳米颗粒,得到了一系列ag修饰的SrFe12O19纳米颗粒。通过PXRD、uv -可见DRS、拉曼光谱、FE-SEM/TEM等表征,证实了m型六方SrFe12O19的形成,并具有均匀分布的Ag NPs。Ag的加入影响了SrFe12O19的磁性和光学性能,当Ag含量增加到10 wt%时,光学带隙略有减少,饱和磁化强度从84 emu/g降低到71 emu/g。Ag修饰并未增强SrFe12O19在可见光下降解染料的光催化活性,但该光催化剂具有磁性可分离性和可重复使用性,且没有明显的效率损失。此外,异质结表现出比单个催化剂快五倍的消毒能力,突出了其在环境和抗菌应用方面的潜力。
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