Bismuth-embedded columnar activated carbon for gaseous radiodine capture

IF 4.6 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Science and Engineering: B Pub Date : 2025-07-01 Epub Date: 2025-03-04 DOI:10.1016/j.mseb.2025.118186
Hao Zou , Hailong Dong , Wanjiang You , Shilong Song , Lei Liao , Gaoling Liang , Ning Pan , Hao Lei , Xiaoqiang Wang
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Abstract

The bismuth-embedded columnar activated carbon (Bi-AC) composite was prepared by the method of self-reduction and investigated for trapping I2 and CH3I. Our findings showed that the bismuth-based compounds mainly existed as simple substance in Bi-AC. The elemental bismuth was regularly spherical in the shape, and mostly embedded on the surface of activated carbon, seldom inside of activated carbon. The capture capacities of I2 and CH3I by the Bi-AC composite was 569.0 ± 14.2 and 232.1 ± 17.7 mg/g, respectively, which was better than that of the commercial silver-based materials. I2 was trapped to form I5- and Bi(IO3)3, while CH3I was catalytically cleaved to form BiOI and I5-. The Bi-AC composite is expected be used as adsorbents of 129I to replace silver-based materials due to its high performance and low cost.
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含铋柱状活性炭用于气态放射性捕获
采用自还原法制备了铋包埋柱状活性炭(Bi-AC)复合材料,并对其捕集I2和CH3I的性能进行了研究。结果表明,铋基化合物主要以单质形式存在于Bi-AC中。元素铋呈规则球形,多嵌埋在活性炭表面,很少在活性炭内部。Bi-AC复合材料对I2和CH3I的捕获量分别为569.0±14.2和232.1±17.7 mg/g,优于商用银基材料。I2被捕获生成I5-和Bi(IO3)3, CH3I被催化裂解生成BiOI和I5-。Bi-AC复合材料性能优异,成本低,有望取代银基材料作为129I的吸附剂。
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阿拉丁
Methyl iodide
来源期刊
Materials Science and Engineering: B
Materials Science and Engineering: B 工程技术-材料科学:综合
CiteScore
5.60
自引率
2.80%
发文量
481
审稿时长
3.5 months
期刊介绍: The journal provides an international medium for the publication of theoretical and experimental studies and reviews related to the electronic, electrochemical, ionic, magnetic, optical, and biosensing properties of solid state materials in bulk, thin film and particulate forms. Papers dealing with synthesis, processing, characterization, structure, physical properties and computational aspects of nano-crystalline, crystalline, amorphous and glassy forms of ceramics, semiconductors, layered insertion compounds, low-dimensional compounds and systems, fast-ion conductors, polymers and dielectrics are viewed as suitable for publication. Articles focused on nano-structured aspects of these advanced solid-state materials will also be considered suitable.
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