Analysis of void formation in Pt-rich γ-γ’ bond-coatings for TBC system application

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-06-01 Epub Date: 2025-02-21 DOI:10.1016/j.corsci.2025.112785
Pauline Audigié , Aurélie Vande Put , Benoit Malard , André Malié , Daniel Monceau
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Abstract

Pt-rich γ-γ’ bond-coatings for thermal barrier coating systems may lead to detrimental pore formation. An extensive analysis of literature on voids nucleation and growth in the different metallic components of several kinds of TBC systems was performed. The study then focused on Pt-rich γ-γ’ bond-coating/Ni-based superalloy systems employing an original statistical analysis of voids formation and spatial distribution through secondary electron microscopy with focused ion beam sequential cross sectioning and synchrotron X-Ray tomography. It was found that pores at the Pt-rich γ-γ’ bond-coating/superalloy interface form due to the Kirkendall effect, with the highest concentration located at the Pt diffusion front.
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TBC体系中富pt γ-γ′键合涂层的空穴形成分析
热障涂层系统的富pt γ-γ键合涂层可能导致有害的孔隙形成。对几种TBC体系中不同金属组分的孔洞形核和生长进行了广泛的文献分析。然后,研究重点是富pt γ-γ键合涂层/ ni基高温合金体系,通过聚焦离子束连续横截面和同步加速器x射线断层扫描的二次电子显微镜对空洞形成和空间分布进行了原始统计分析。结果表明,由于Kirkendall效应,在富Pt的γ-γ′键合涂层/高温合金界面处形成气孔,且气孔浓度最高的部位位于Pt扩散前沿。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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