Lucie Pirot-Berson , Romain Couderc , Romain Bodeux , Frédéric Jay , Paul Lefillastre , Julien Dupuis
{"title":"Study and mitigation of moisture-induced degradation in SHJ modules by modifying cell structure","authors":"Lucie Pirot-Berson , Romain Couderc , Romain Bodeux , Frédéric Jay , Paul Lefillastre , Julien Dupuis","doi":"10.1016/j.solmat.2025.113557","DOIUrl":null,"url":null,"abstract":"<div><div>Silicon heterojunction (SHJ) modules are known for their high efficiency and are expected to gain significant market share in the coming years. In terms of reliability, SHJ technology can be sensitive to moisture-induced degradation and sodium-induced degradation from sodium ions released from the glass. In these degradation mechanisms, the different layers of the SHJ cell structure could play an important role that needs to be understood. This work investigates the moisture-induced degradation in SHJ modules under damp heat (DH) by varying the cell structure with different types and thicknesses of transparent conductive oxide (TCO). Due to the migration of sodium ions, the thinner the TCO layer, the higher the degradation induced. The protective effect of dielectric capping layers is also investigated, allowing at the same time to reduce the indium consumption, which is a crucial issue for SHJ cells. These layers provide protection against degradation. Finally, a schematic model is proposed to summarize the degradation mechanisms, including the effect of cell structure on them.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"285 ","pages":"Article 113557"},"PeriodicalIF":6.3000,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024825001588","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Silicon heterojunction (SHJ) modules are known for their high efficiency and are expected to gain significant market share in the coming years. In terms of reliability, SHJ technology can be sensitive to moisture-induced degradation and sodium-induced degradation from sodium ions released from the glass. In these degradation mechanisms, the different layers of the SHJ cell structure could play an important role that needs to be understood. This work investigates the moisture-induced degradation in SHJ modules under damp heat (DH) by varying the cell structure with different types and thicknesses of transparent conductive oxide (TCO). Due to the migration of sodium ions, the thinner the TCO layer, the higher the degradation induced. The protective effect of dielectric capping layers is also investigated, allowing at the same time to reduce the indium consumption, which is a crucial issue for SHJ cells. These layers provide protection against degradation. Finally, a schematic model is proposed to summarize the degradation mechanisms, including the effect of cell structure on them.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.