Effect of magnetite nanoparticle size and concentration on microbiologically influenced corrosion of X70 steel by Desulfovibrio vulgaris

IF 5.6 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2025-03-07 DOI:10.1016/j.electacta.2025.145992
Mengfen Guo, Fei Xie, Dan Wang, Dongxu Sun, Ming Wu
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Abstract

This study investigates the impact of magnetic nanoparticle (MNP) size and concentration on the microbiologically influenced corrosion (MIC) of X70 steel, employing electrochemical tests, microscopic characterization, and sulfate concentration measurements. The results show that a 50 ppm concentration of MNPs increased the MIC rate by 122.1 %, with particle size having a minimal effect. High concentrations of MNPs significantly reduced anodic electron transfer resistance and enhanced cathodic consumption, thereby accelerating extracellular electron transfer (EET)- mediated MIC of X70 steel. These findings offer crucial insights into the role of magnetite in MIC mechanisms and provide a scientific foundation for improving the management of corrosion in oil and gas pipelines.
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纳米磁铁矿粒径和浓度对普通脱硫弧菌腐蚀X70钢的影响
本研究通过电化学测试、微观表征和硫酸盐浓度测量,研究了磁性纳米颗粒(MNP)的大小和浓度对X70钢微生物影响腐蚀(MIC)的影响。结果表明,50 ppm浓度的MNPs使MIC率提高了122.1%,粒径对MIC率的影响最小。高浓度MNPs显著降低了阳极电子转移电阻,增加了阴极消耗,从而加速了X70钢的细胞外电子转移(EET)介导的MIC。这些发现为了解磁铁矿在MIC机制中的作用提供了重要见解,并为改善油气管道腐蚀管理提供了科学基础。
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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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