Ultrasensitive terahertz metasensor integrated with EIT-like coupling and liquid flow micro-channels for organic solvent detection and identification

IF 4.6 2区 化学 Q1 SPECTROSCOPY Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Pub Date : 2025-07-05 Epub Date: 2025-03-07 DOI:10.1016/j.saa.2025.125996
Huihan Tian , Yonggang Zhang , Lanju Liang , Xin Yan , Haiyun Yao , Ziqun Wang , Zhenhua Li , Xiaofei Hu , Yuanping Li , Jintao Wu , Shiwu Ma , Zhaoyang Shi , Qingyi Wang , Yongzhen Chen , Fei Huai
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Abstract

Terahertz (THz)-based metasurface sensors offer potential and extensive application prospects for organic solvent detection. This study proposed a liquid sensor comprising an electromagnetically induced transparency (EIT)-like THz metasurface covered by a channel. The designed device can exploit variations in the EIT-like resonance peaks to distinguish between the concentrations of three types of organic solvents (ethanol(ET), acetone(AC), and isopropyl alcohol(IPA)). The experimental results indicate that the maximum sensitivity values are 0.442 for ET, 0.365for AC, and 0.129 for IPA. A wavelet transform method was proposed to convert one-dimensional frequency-dependent transmission spectra into two-dimensional coefficient intensity cards, facilitating significant differentiation between solvent concentrations. Radar charts integrating multiple transmission characteristic points were employed to provide multidimensional information to identify three types of organic solutions. This study proposes a liquid sensor for the rapid, label-free detection and identification of organic solvents of different concentrations and types.

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集成了eit耦合和液体流动微通道的超灵敏太赫兹超灵敏传感器用于有机溶剂的检测和鉴定
基于太赫兹(THz)的超表面传感器在有机溶剂检测中具有广阔的应用前景。本研究提出了一种由通道覆盖的类似电磁感应透明(EIT)的太赫兹超表面组成的液体传感器。所设计的装置可以利用类似eit的共振峰的变化来区分三种有机溶剂(乙醇(ET),丙酮(AC)和异丙醇(IPA))的浓度。实验结果表明,ET、AC和IPA的最大灵敏度分别为0.442、0.365和0.129。提出了一种小波变换方法,将一维频率相关透射光谱转换为二维系数强度卡,使溶剂浓度之间的区分更加明显。利用集成多个传输特征点的雷达图提供多维信息,识别出三种类型的有机解决方案。本研究提出了一种液体传感器,用于快速,无标签检测和识别不同浓度和类型的有机溶剂。
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来源期刊
CiteScore
8.40
自引率
11.40%
发文量
1364
审稿时长
40 days
期刊介绍: Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science. The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments. Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate. Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to: Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences, Novel experimental techniques or instrumentation for molecular spectroscopy, Novel theoretical and computational methods, Novel applications in photochemistry and photobiology, Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.
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