{"title":"Kinetic Features of Radical Ring-Opening Polymerization of Ketene Acetals","authors":"M. Yu. Zaremski, E. E. Aliev","doi":"10.1134/S156009042460147X","DOIUrl":null,"url":null,"abstract":"<p>This paper is the first generalization of the material accumulated in the kinetic study of the ring-opening polymerization of cyclic ketene acetals. The main attention is focused on the difference between the kinetics of radical polymerization of these monomers and the kinetics of polymerization of vinyl monomers. The difference in the mechanisms of elementary events of chain initiation and termination is revealed. Kinetic features of the controlled polymerization of cyclic ketene acetals occurring by reversible inhibition, atom transfer, and reversible-addition fragmentation chain-transfer mechanisms are considered.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"66 4","pages":"445 - 466"},"PeriodicalIF":1.0000,"publicationDate":"2025-01-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S156009042460147X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
This paper is the first generalization of the material accumulated in the kinetic study of the ring-opening polymerization of cyclic ketene acetals. The main attention is focused on the difference between the kinetics of radical polymerization of these monomers and the kinetics of polymerization of vinyl monomers. The difference in the mechanisms of elementary events of chain initiation and termination is revealed. Kinetic features of the controlled polymerization of cyclic ketene acetals occurring by reversible inhibition, atom transfer, and reversible-addition fragmentation chain-transfer mechanisms are considered.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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