Mikhail Boym, Roman A Pototskiy, Evgeniya Podyacheva, Dmitry V. Muratov, Yulia V. Nelyubina, Dmitry S. Perekalin
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引用次数: 0
Abstract
Natural R-carvone was converted into chiral 1-aryl-2-methyl-5-isopropyl-cyclohexadienes using cross-coupling reaction as a key step. These dienes react with RuCl3 to give planar-chiral complexes [(arene)RuCl2]2 in 70-75% yield. Complex [(1-Ph-2-Me-5-iPr-C6H3)RuCl2]2, a chiral analogue of the classical catalyst [(cymene)RuCl2]2, promotes C−H activation of N-methoxy-benzamide and intramolecular insertion of diazo compound into C−H bond, but gives products with low stereoselectivity.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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