Shape memory polybutene-1 alloy with superior high-temperature resistances to creep and raw petroleum

IF 4.5 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-04-17 Epub Date: 2025-03-11 DOI:10.1016/j.polymer.2025.128266
Xiangyuan Meng, Huifang Ma, Yaping Ma, Chenguang Liu, Aihua He
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Abstract

High-temperature resistant shape memory polyolefins, which also exhibit resistances to creep and raw petroleum, are highly crucial for the pipelines in severe environments, like high temperature, high pressure and petroleum medium. Herein, a series of crosslinked polybutene-1 alloys (PBA-X) were firstly fabricated, which presented excellent high-temperature resistances to creep and raw petroleum at 85 °C, as well as outstanding shape memory behaviors like 93.7–100.0 % shape recovery ratio (Rr), 90.6–98.4 % shape fixation ratio (Rf), and easy recovered from varied programmed three-dimensional (3D) shapes through thermal stimulation. PBA-X are anticipated to offer significant potential as innovative pipeline lining materials for deep-ocean petroleum transportation systems.

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形状记忆型聚丁烯-1合金,具有优异的耐高温蠕变和原油性能
耐高温形状记忆聚烯烃还具有抗蠕变和抗原油的特性,对于高温、高压和石油介质等恶劣环境下的管道至关重要。本文首先制备了一系列交联聚丁烯-1合金(PBA-X),该合金具有优异的耐蠕变和85℃原油高温性能,具有93.7 ~ 100.0%的形状恢复率(Rr)和90.6% ~ 98.4%的形状固定率(Rf)等优异的形状记忆性能,并且易于通过热刺激从各种编程三维(3D)形状中恢复。PBA-X有望成为深海石油运输系统的创新型管道衬里材料。
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文献相关原料
公司名称
产品信息
阿拉丁
Triallyl isocyanurate (TAIC)
阿拉丁
Bis(1-(tert-butylperoxy)-1-methylethyl)-benzene (BIPB)
来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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