Enhancement of Impact Resistance and Shock Wave Protection in Strain Rate-Reinforced Leather Composite

IF 4.3 3区 化学 Q2 POLYMER SCIENCE Macromolecular Rapid Communications Pub Date : 2025-03-10 DOI:10.1002/marc.202401135
Ziyang Fan, Yu Wang, Xiangyang Yao, Yue Yao, Xinglong Gong, Wei Yang, Honghao Ma, Shouhu Xuan
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Abstract

This work develops the Leather/SSG composite with a laminated structure that consists of flexible leather and rate-dependent shear stiffening gel (SSG), which exhibits superior impact resistance and shock wave protection performance. The SSG is tightly bound to the leather fiber network through hydrogen bonding interactions between the interfaces. Owing to the phase change energy absorption effect of SSG and the synergizing impact force dispersion along the disordered fibers, the Leather/SSG can effectively alleviate the impact force (52%) and shows high energy absorption (0.86–0.95). Besides, Leather/SSG exhibits strain rate enhancement effects with high strain rate impact and it can effectively dissipate stress wave energy by blocking the transmission of stress waves. Moreover, due to the interface structure of soft–hard transition, the Leather/SSG effectively reduces shock wave pressure and positive impulse under the explosive loading. Simultaneously, the influence of impact sequence in Leather/SSG on impact resistance and shock wave absorption is analyzed, confirming the advantage of the leather fiber side being impacted first. These results can provide an important theoretical basis and experimental reference for designing soft/hard impact-resistant composite structures.

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应变率增强皮革复合材料抗冲击性和冲击波防护性能的提高。
这项工作开发了皮革/SSG复合材料,其层压结构由柔性皮革和速率相关的剪切硬化凝胶(SSG)组成,具有优异的抗冲击性和冲击波保护性能。SSG通过界面之间的氢键相互作用与皮革纤维网络紧密结合。由于SSG的相变吸能效应和协同冲击力沿无序纤维分散,皮革/SSG能有效缓解冲击力(52%),并表现出较高的能量吸收(0.86 ~ 0.95)。此外,皮革/SSG在高应变率冲击下表现出应变率增强效果,可以通过阻断应力波的传播有效地耗散应力波能量。此外,由于软-硬过渡的界面结构,皮革/SSG有效地降低了爆炸载荷下的冲击波压力和正冲量。同时,分析了皮革/SSG中冲击顺序对其抗冲击性和冲击波吸收的影响,确定了皮革纤维侧优先受到冲击的优势。研究结果可为设计软硬抗冲击复合材料结构提供重要的理论依据和实验参考。
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来源期刊
Macromolecular Rapid Communications
Macromolecular Rapid Communications 工程技术-高分子科学
CiteScore
7.70
自引率
6.50%
发文量
477
审稿时长
1.4 months
期刊介绍: Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.
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