Improved oxidation behavior of M–20Cr–20Ta (M: Ni, Fe, Co) ternary alloys by formation of complex Cr–Ta-based oxides

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-03-07 DOI:10.1016/j.corsci.2025.112847
Chongchong Tang, Björn Schäfer, Carsten Schroer, Bronislava Gorr
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Abstract

The oxidation behavior and microstructural evolution of M–20Cr–20Ta (M: Ni, Fe, Co) alloys are investigated at 1000°C and 1200°C in Ar–20 vol% O2. High-temperature oxidation results in growth of bi-layered oxide scales, featuring an outer Cr₂O₃ layer and an inner Cr–Ta oxide layer. The Cr–Ta oxide layer consists of two distinct phases: CrTaO₄ and CrTa₂O₆. Significant improvements in oxidation resistance are found for Co and Fe alloys, in consequence of formation of the Cr–Ta oxides. At 1200°C, oxidation kinetics approach a cubic growth law after an initial transient stage, underscoring the exceptional protective capabilities of the Cr–Ta oxides.
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通过形成配合的cr - ta基氧化物,改善了M - 20cr - 20ta (M: Ni, Fe, Co)三元合金的氧化行为
研究了M - 20cr - 20ta (M: Ni, Fe, Co)合金在Ar-20 vol% O2中1000℃和1200℃的氧化行为和显微组织演变。高温氧化导致双层氧化层的生长,其特征是外层的Cr₂O₃层和内部的Cr - ta氧化层。Cr-Ta氧化物层由两种不同的相组成:crta4和crta2o₆。由于形成了Cr-Ta氧化物,Co和Fe合金的抗氧化性得到了显著改善。在1200°C时,氧化动力学在初始瞬态阶段后接近立方生长规律,强调了Cr-Ta氧化物的特殊保护能力。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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