Preparation of glass fiber-PVA assisted secondary growth of silver nanowires and flexible conductive films

IF 4.7 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Chemistry and Physics Pub Date : 2025-03-09 DOI:10.1016/j.matchemphys.2025.130685
Weimin Yan, Chengmin Hou
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Abstract

Flexible electronics demand conductive films with high stability and conductivity. However, silver nanowires (AgNWs) face challenges like agglomeration and inconsistent morphology. In this study, AgNWs were synthesized via a two-step process: (1) preliminary growth using a glass fiber template and polyol method (diameter: 0.2–0.4 μm, length: 1–6 μm), and (2) secondary growth by mixing AgNWs with PVA solution followed by heat treatment. The secondary growth enhanced nanowire dimensions (diameter: 5–7 μm, length: 100–200 μm) and conductivity. The optimized film exhibited stable resistance (4 MΩ) after 5000 bends (90° and 180°) and achieved optimal performance at 100 °C/30 min. This method provides a scalable solution for flexible electronics.

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玻璃纤维-聚乙烯醇辅助银纳米线和柔性导电膜二次生长的制备
柔性电子产品需要具有高稳定性和导电性的导电薄膜。然而,银纳米线(AgNWs)面临着团聚和形态不一致等挑战。在本研究中,AgNWs的合成分为两步:(1)采用玻璃纤维模板和多元醇法(直径:0.2-0.4 μm,长度:1 - 6 μm)进行初步生长,(2)将AgNWs与PVA溶液混合并进行热处理进行二次生长。二次生长增强了纳米线的尺寸(直径5 ~ 7 μm,长度100 ~ 200 μm)和电导率。优化后的薄膜在5000次弯曲(90°和180°)后表现出稳定的电阻(4 MΩ),并在100°C/30分钟下达到最佳性能。该方法为柔性电子产品提供了可扩展的解决方案。
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阿拉丁
FeCl3·6H2O
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PVA
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PVP
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Polyvinyl alcohol
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Ethylene glycol
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Ferric chloride
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Polyvinylpyrrolidone
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Silver nitrate
来源期刊
Materials Chemistry and Physics
Materials Chemistry and Physics 工程技术-材料科学:综合
CiteScore
8.70
自引率
4.30%
发文量
1515
审稿时长
69 days
期刊介绍: Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.
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