Characterization of thermal, chemical, mechanical, and fatigue behavior of 3D printed ABS-based elastomeric blends: ABS/EVA and ABS/TPU

IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Polymer Testing Pub Date : 2025-04-01 Epub Date: 2025-03-10 DOI:10.1016/j.polymertesting.2025.108763
Hamdi Kuleyin , Selahattin Budak , Ömer Barışkan Yasan , Recep Gümrük
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Abstract

The polymer blending method is widely used to obtain balanced mechanical properties and structural performance in many engineering applications. This study investigates the influence of Ethylene-Vinyl Acetate (EVA), and Thermoplastic Polyurethane (TPU) composition ratios on the thermal, chemical, viscoelastic, mechanical, and fatigue life behavior of Acrylonitrile-Butadiene-Styrene (ABS) based elastomeric blends. For this purpose, structural and mechanical properties of the blend material depending on their composition ratio were carried out through a series of characterization analyses, and tensile and fatigue tests. The findings indicated that ABS/EVA and ABS/TPU blends formed an immiscible structure. In addition, it was determined that the storage modulus of the blend with 10 % TPU improved because of the presence of new absorption peaks in the structure. The mechanical properties such as elastic modulus, yield strength, and ultimate tensile strength decreased concerning neat ABS with an increase in the EVA and TPU composition ratio for blend materials. However, the elongation to break was achieved approximately 6 times increasing with an increase in the TPU ratio for ABS/TPU blends. It was determined that the fatigue strength value in ABS/EVA and ABS/TPU blends decreased with the decrease in ABS composition ratio in the blend system. However, it was found that fatigue life improved by 25 % compared to ABS at low-stress amplitude for 10 % TPU additive. Finally, it can be revealed that the ABS-based elastomeric blends can be used to obtain desired properties according to their composition ratios for different applications.
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3D打印ABS-based弹性体共混物:ABS/EVA和ABS/TPU的热、化学、机械和疲劳性能表征
聚合物共混方法在许多工程应用中被广泛用于获得平衡的力学性能和结构性能。本研究探讨了乙烯-醋酸乙烯(EVA)和热塑性聚氨酯(TPU)的组成比对丙烯腈-丁二烯-苯乙烯(ABS)基弹性体共混物的热、化学、粘弹性、力学和疲劳寿命行为的影响。为此,通过一系列的表征分析、拉伸和疲劳试验,对不同成分配比的共混材料的结构和力学性能进行了研究。结果表明,ABS/EVA和ABS/TPU共混物形成了不混相结构。此外,由于在结构中存在新的吸收峰,确定了10% TPU共混物的存储模量得到改善。随着EVA和TPU配比的增加,纯ABS的弹性模量、屈服强度和极限抗拉强度等力学性能均有所下降。然而,随着TPU比例的增加,ABS/TPU共混物的断裂伸长率提高了约6倍。结果表明,ABS/EVA和ABS/TPU共混体系的疲劳强度值随着ABS配比的降低而降低。然而,与ABS相比,添加10% TPU的ABS在低应力幅下的疲劳寿命提高了25%。结果表明,abs基弹性体共混物可以根据其组成比例获得所需的性能。
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来源期刊
Polymer Testing
Polymer Testing 工程技术-材料科学:表征与测试
CiteScore
10.70
自引率
5.90%
发文量
328
审稿时长
44 days
期刊介绍: Polymer Testing focuses on the testing, analysis and characterization of polymer materials, including both synthetic and natural or biobased polymers. Novel testing methods and the testing of novel polymeric materials in bulk, solution and dispersion is covered. In addition, we welcome the submission of the testing of polymeric materials for a wide range of applications and industrial products as well as nanoscale characterization. The scope includes but is not limited to the following main topics: Novel testing methods and Chemical analysis • mechanical, thermal, electrical, chemical, imaging, spectroscopy, scattering and rheology Physical properties and behaviour of novel polymer systems • nanoscale properties, morphology, transport properties Degradation and recycling of polymeric materials when combined with novel testing or characterization methods • degradation, biodegradation, ageing and fire retardancy Modelling and Simulation work will be only considered when it is linked to new or previously published experimental results.
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