Thermal Properties of Extrapure Glasses of the Ga15Ge10Te75–xIx System

IF 0.7 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Inorganic Materials Pub Date : 2025-03-13 DOI:10.1134/S0020168524701279
D. O. Patrushev, A. M. Kut’in, A. D. Plekhovich, K. V. Balueva, A. P. Velmuzhov, E. A. Tyurina, I. I. Evdokimov, A. E. Kurganova
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Abstract

We have prepared extrapure Ga15Ge10Te75–xIx (x = 0–6 at %) glasses with a concentration of 31 impurity elements no higher than 0.2 ppm and studied the effect of iodine on the characteristic temperatures, crystallization resistance, thermal expansion, and density of the glasses. The results have been interpreted in terms of the structural connectivity approach. A technique has been proposed for dynamic dilatometry data processing with the aim of determining the linear thermal expansion coefficient (LTEC) as a function of temperature. The LTEC of the Ga15Ge10Te75–xIx glasses has been determined as a function of temperature in the range from 293 to 412 K.

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Ga15Ge10Te75-xIx体系外渗玻璃的热性能
制备了31种杂质元素浓度不高于0.2 ppm的Ga15Ge10Te75-xIx (x = 0-6 at %)玻璃,研究了碘对玻璃的特征温度、结晶电阻、热膨胀和密度的影响。研究结果用结构连通性方法进行了解释。提出了一种动态膨胀数据处理技术,其目的是确定线性热膨胀系数(LTEC)作为温度的函数。测定了ga15ge10te75 - 19玻璃的LTEC随温度在293 ~ 412 K范围内的变化规律。
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来源期刊
Inorganic Materials
Inorganic Materials 工程技术-材料科学:综合
CiteScore
1.40
自引率
25.00%
发文量
80
审稿时长
3-6 weeks
期刊介绍: Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.
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