Tai Li, Zhaoying Chen, Tao Wang, Wei Luo, Renchun Tao, Zexing Yuan, Tongxin Lu, Yucheng Guo, Ye Yuan, Shangfeng Liu, Junjie Kang, Ping Wang, Bowen Sheng, Fang Liu, Qi Wang, Shengqiang Zhou, Bo Shen, Xinqiang Wang
{"title":"Residual Al Adatoms Driven Epitaxy of AlGaN QWs for High-Performance UV LEDs","authors":"Tai Li, Zhaoying Chen, Tao Wang, Wei Luo, Renchun Tao, Zexing Yuan, Tongxin Lu, Yucheng Guo, Ye Yuan, Shangfeng Liu, Junjie Kang, Ping Wang, Bowen Sheng, Fang Liu, Qi Wang, Shengqiang Zhou, Bo Shen, Xinqiang Wang","doi":"10.1002/adma.202501601","DOIUrl":null,"url":null,"abstract":"AlGaN-based ultraviolet (UV) light-emitting diodes (LEDs) experience a notable reduction in efficiency within the 280–330 nm wavelength range, known as the “UVB gap”. Given the extensive applications of UV LEDs in this wavelength range, it is imperative to bridge this efficiency gap. In this study, a strategy facilitated by the presence of residual Al adatoms is introduced to simultaneously improve the integration of Ga-adatoms and the migration of Al/Ga-adatoms during the growth of low-Al-composition AlGaN quantum wells (QWs) even at high temperatures comparable to those used for high-Al-composition AlGaN quantum barriers. This growth strategy enables the epitaxy of high-quality AlGaN QWs with a wide tunable emission wavelength range across the UVB gap. Utilizing this approach, high-efficiency UV LEDs that effectively bridge the UVB gap are developed. Furthermore, benefiting from this QWs growth configuration, these UV LEDs exhibit an exceptionally long L<sub>70</sub> lifetime, marking a significant step forward in the growth technology of AlGaN QWs and expanding the application possibilities of UV LEDs.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"183 1","pages":""},"PeriodicalIF":27.4000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202501601","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
AlGaN-based ultraviolet (UV) light-emitting diodes (LEDs) experience a notable reduction in efficiency within the 280–330 nm wavelength range, known as the “UVB gap”. Given the extensive applications of UV LEDs in this wavelength range, it is imperative to bridge this efficiency gap. In this study, a strategy facilitated by the presence of residual Al adatoms is introduced to simultaneously improve the integration of Ga-adatoms and the migration of Al/Ga-adatoms during the growth of low-Al-composition AlGaN quantum wells (QWs) even at high temperatures comparable to those used for high-Al-composition AlGaN quantum barriers. This growth strategy enables the epitaxy of high-quality AlGaN QWs with a wide tunable emission wavelength range across the UVB gap. Utilizing this approach, high-efficiency UV LEDs that effectively bridge the UVB gap are developed. Furthermore, benefiting from this QWs growth configuration, these UV LEDs exhibit an exceptionally long L70 lifetime, marking a significant step forward in the growth technology of AlGaN QWs and expanding the application possibilities of UV LEDs.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.