Intramolecular through-space heavy-atom effect in π-stacked MR-TADF emitters

IF 19.6 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chem Pub Date : 2025-04-10 Epub Date: 2025-03-13 DOI:10.1016/j.chempr.2024.11.015
Sheng-Yi Yang , Cheng Liu , Fei Wang , Ben Zhong Tang
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引用次数: 0

Abstract

In this issue of Chem, Jiang and colleagues utilized a spiro-fluorene unit as a π-bridge to construct a series of π-stacked multi-resonance thermally activated delayed fluorescence emitters. By introducing different heavy atoms through chemical bonding, they revealed the impact of the intramolecular through-space heavy-atom effect on the optoelectronic properties of the molecules.
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π堆叠MR-TADF发射体分子内穿越空间重原子效应
在本期Chem中,Jiang等利用螺芴单元作为π桥,构建了一系列π堆叠的多共振热激活延迟荧光发射器。通过化学键引入不同的重原子,他们揭示了分子内穿越空间的重原子效应对分子光电性能的影响。
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来源期刊
Chem
Chem Environmental Science-Environmental Chemistry
CiteScore
32.40
自引率
1.30%
发文量
281
期刊介绍: Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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