Evolutions of Both Temperature Field and Convection Field During GaInSb THM and VB Crystal Growths and Influences of Temperature Gradient

IF 1.9 4区 材料科学 Q3 Chemistry Crystal Research and Technology Pub Date : 2025-01-23 DOI:10.1002/crat.202400202
Pei Wang, Bowen Wang, Leran Zhao, Ming Liu, Jian Liu, Xinhu Zhang, Juncheng Liu
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Abstract

III-V semiconductor compound crystals are widely used in the advanced infrared detectors and lasers etc. The traveling heater method (THM) and the vertical Bridgman method (VB) are two important methods to grow high-quality, especially low dislocation density bulk single crystals, in which the furnace temperature gradient GTH, usually plays a key role determining the dislocation density. This work simulates numerically GaInSb crystal growths with both THM and VB, displaying the evolutions of both the temperature field inside the crucible domain and the flow field in the melt in detail, investigating the influences of GTH on the temperature and the flow fields, especially on the temperature gradient at the front of crystal growth interface and its shape. The results show that both of them are more dependent on GTH during THM crystal growth than during VB one. Furthermore, this work focuses on the impact of the mushy zone in the front of growth interface during the ternary compounds’ crystal growth, which has been almost always ignored in the previous numerical simulation works.

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GaInSb THM和VB晶体生长过程中温度场和对流场的演变及温度梯度的影响
III-V型半导体复合晶体广泛应用于先进的红外探测器和激光器等。行走加热器法(THM)和垂直Bridgman法(VB)是生长高质量特别是低位错密度块状单晶的两种重要方法,其中炉温梯度GTH通常是决定位错密度的关键因素。本文利用THM和VB对GaInSb晶体生长过程进行了数值模拟,详细地展示了坩埚内温度场和熔体内流场的演变,研究了GTH对温度场和流场的影响,特别是对晶体生长界面前端温度梯度及其形状的影响。结果表明,在THM晶体生长过程中,两者对GTH的依赖性大于VB晶体生长过程。此外,本工作还重点研究了三元化合物晶体生长过程中生长界面前端糊化带的影响,这在以往的数值模拟工作中几乎总是被忽略。
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来源期刊
CiteScore
2.50
自引率
6.70%
发文量
121
审稿时长
1.9 months
期刊介绍: The journal Crystal Research and Technology is a pure online Journal (since 2012). Crystal Research and Technology is an international journal examining all aspects of research within experimental, industrial, and theoretical crystallography. The journal covers the relevant aspects of -crystal growth techniques and phenomena (including bulk growth, thin films) -modern crystalline materials (e.g. smart materials, nanocrystals, quasicrystals, liquid crystals) -industrial crystallisation -application of crystals in materials science, electronics, data storage, and optics -experimental, simulation and theoretical studies of the structural properties of crystals -crystallographic computing
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