Duo Liu , Rui Jiang , Yanyu Song , Naibin Chen , Tao Wang , Hong Bian , Wei Fu , Baoqiang Wang , Xiaoguo Song
{"title":"Low-temperature brazing of SiCp/Al composites with Bi2O3-B2O3-ZnO-SiO2-Al2O3 glass in air","authors":"Duo Liu , Rui Jiang , Yanyu Song , Naibin Chen , Tao Wang , Hong Bian , Wei Fu , Baoqiang Wang , Xiaoguo Song","doi":"10.1016/j.matchar.2025.114932","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, low-melting Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-ZnO-SiO<sub>2</sub>-Al<sub>2</sub>O<sub>3</sub> (BBZSA) glass was adopted to braze SiC<sub>p</sub>/Al composite, and the effects of brazing temperature and holding time on the microstructure and mechanical properties of the SiC<sub>p</sub>/Al joint were investigated. The BBZSA glass started to spread and wet on the surface of SiC<sub>p</sub>/Al composite at the temperature of 480 °C. The typical microstructure at this temperature was SiC<sub>p</sub>/Al + Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-ZnO glass + Bi<sub>24</sub>B<sub>2</sub>O<sub>39</sub> + Si<sub>2</sub>Al<sub>2</sub>O<sub>7</sub> + SiO<sub>2</sub>, and the interface was bonded by the intermolecular force between the Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-ZnO (BBZ) glass and SiC<sub>p</sub>/Al composite. Besides, the precipitation of the Bi<sub>24</sub>B<sub>2</sub>O<sub>39</sub> phase improved the mechanical properties of the joint with a maximum strength of 17.3 MPa, and the fractures all occurred in the Bi<sub>2</sub>O<sub>3</sub>-B<sub>2</sub>O<sub>3</sub>-ZnO (BBZ) glass of the brazing seam. The proof-of-concept study on the brazing of SiC<sub>p</sub>/Al composite with BBZSA glass provides insights in the further development of ceramic/metal composite joining.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"223 ","pages":"Article 114932"},"PeriodicalIF":4.8000,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325002219","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
Abstract
In this study, low-melting Bi2O3-B2O3-ZnO-SiO2-Al2O3 (BBZSA) glass was adopted to braze SiCp/Al composite, and the effects of brazing temperature and holding time on the microstructure and mechanical properties of the SiCp/Al joint were investigated. The BBZSA glass started to spread and wet on the surface of SiCp/Al composite at the temperature of 480 °C. The typical microstructure at this temperature was SiCp/Al + Bi2O3-B2O3-ZnO glass + Bi24B2O39 + Si2Al2O7 + SiO2, and the interface was bonded by the intermolecular force between the Bi2O3-B2O3-ZnO (BBZ) glass and SiCp/Al composite. Besides, the precipitation of the Bi24B2O39 phase improved the mechanical properties of the joint with a maximum strength of 17.3 MPa, and the fractures all occurred in the Bi2O3-B2O3-ZnO (BBZ) glass of the brazing seam. The proof-of-concept study on the brazing of SiCp/Al composite with BBZSA glass provides insights in the further development of ceramic/metal composite joining.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.