Resistance of a Polymer Composition with a Biocidal Effect to the Exposure of a Tropical Marine Environment

IF 0.58 Q4 Materials Science Polymer Science, Series D Pub Date : 2025-03-16 DOI:10.1134/S1995421224702022
E. A. Bobina, M. P. Danilaev, T. R. Deberdeev, O. N. Il’inskaya, S. A. Karandashov, V. A. Kuklin, Lê Hõng Quân, G. Yu. Yakovleva
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Abstract

The results of a study of the resistance of a polymer composition based on epoxy resin with a biocidal effect to the exposure of the marine environment of the tropical climate have been presented. The biocidal effect was achieved by using dispersed copper(I) oxide particles, both encapsulated with polylactide and unencapsulated particles. It has been shown that the highest efficiency of the biocidal effect, along with the best strength indicators of such a composition, is observed at a mass fraction of encapsulated particles of ~0.7–0.8%. The tensile strength of the corresponding composition increases by 30% compared to the unfilled polymer. This is due to the formation of additional cross-links in the polymer network as a result of the interaction of the encapsulated particles with the polymer. A twofold decrease in strength characteristics has been noted after climatic tests. This is due to severe damage to the surface of the samples under study. The paper shows that the proposed approach to creating a biocidal composition using encapsulated particles is more effective when using such materials in the air, rather than in the sea environment of a tropical climate.

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具有生物杀灭作用的聚合物组合物对热带海洋环境暴露的抵抗力
本文介绍了一种具有生物杀灭作用的环氧树脂聚合物组合物对热带气候海洋环境暴露的抗性研究结果。采用聚丙交酯包封和未包封的分散氧化铜颗粒达到了杀菌效果。研究表明,当包封颗粒的质量分数为~ 0.7-0.8%时,该组合物的杀菌效果最高,强度指标也最好。与未填充的聚合物相比,相应组合物的抗拉强度提高了30%。这是由于包封颗粒与聚合物相互作用的结果,在聚合物网络中形成了额外的交联。在气候试验后,强度特性下降了两倍。这是由于所研究样品的表面受到严重破坏。这篇论文表明,当在空气中使用这种材料而不是在热带气候的海洋环境中使用这种材料时,使用封装颗粒制造生物杀灭成分的拟议方法更有效。
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来源期刊
Polymer Science, Series D
Polymer Science, Series D Materials Science-Polymers and Plastics
CiteScore
0.80
自引率
0.00%
发文量
87
期刊介绍: Polymer Science, Series D  publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.
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