A. P. Filippov, T. Yu. Kirila, S. V. Rodchenko, M. A. Golovina, N. D. Kozina, A. V. Tenkovtsev
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引用次数: 0
Abstract
Block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine and poly-2-methyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine. Using NMR spectroscopy, it was determined that in copolymers the component fraction varies in a tenfold range. The hydrodynamic characteristics of the synthesized copolymers were determined using molecular hydrodynamics and optics methods and it was shown that they are flexible-chain polymers with an equilibrium rigidity of about 2 nm. The behavior of block copolymers in water-salt solutions depends on the content of blocks: an increase in the fraction of the more hydrophobic poly-2-isopropyl-5,6-dihydrooxazine leads to a decrease in the phase separation temperature and LCST. The addition of NaCl leads to a slight decrease in the phase separation temperature.
期刊介绍：
Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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