Multifunctional Nonwoven Conductive Materials Based on Polyaniline and Commodity Polymers

IF 0.8 Q3 Engineering Nanotechnologies in Russia Pub Date : 2025-03-16 DOI:10.1134/S2635167624601311
S. N. Malakhov, I. M. Demina, S. N. Chvalun
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Abstract

Hybrid electrically conductive materials were obtained by the synthesis of a polyaniline-based conductive layer on fibrous matrices. Nonconductive nonwoven fabrics with fibers 0.5–13.5 μm in diameter were produced by electrospinning from solutions and melts of a number of commodity polymers. The influence of the surface properties of the initial matrices on the polyaniline synthesis process and electrophysical characteristics of the hybrid conductive materials was studied. It was shown that for highly hydrophobic matrices synthesis of the conductive layer occurs only on the upper layers of fibers, which causes much lower conductivity (10–4 S/cm and less) compared to wettable matrices, where synthesis occurs over the entire volume of the nonwoven fabric, and conductivity reaches 5 × 10–2 S/cm.

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基于聚苯胺和商品聚合物的多功能非织造导电材料
通过在纤维基体上合成聚苯胺基导电层,制备了杂化导电材料。采用静电纺丝法制备了直径为0.5 ~ 13.5 μm的非导电非织造布。研究了初始基体的表面性质对聚苯胺合成过程和杂化导电材料电物理特性的影响。结果表明,对于高度疏水的基质,导电层的合成只发生在纤维的上层,与可湿性基质相比,其导电性要低得多(10-4 S/cm甚至更低),而可湿性基质的合成发生在无纺布的整个体积上,其导电性达到5 × 10-2 S/cm。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
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0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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