Cover Feature: Unveiling the Catalytic Activity of Nickel(II) Complexes of Pentadentate Ligands in Aromatic Oxidations (ChemCatChem 6/2025)

IF 3.9 3区 化学 Q2 CHEMISTRY, PHYSICAL ChemCatChem Pub Date : 2025-03-17 DOI:10.1002/cctc.202580602
Anjana Rajeev, Sethuraman Muthuramalingam, Visvesvarar Pitchai Murugan, Miquel Costas, Prabha Vadivelu, Muniyandi Sankaralingam
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Abstract

The Cover Feature depicts the hydroxylation of benzene to phenol in the presence of a nickel pentadentate catalyst and hydrogen peroxide. The highly inert nature of the C─H bonds of benzene is represented by a spherical cage secured with a locked chain. However, the powerful nickel catalyst and oxidant act as a key, facilitating the selective oxidation of one of the C─H bonds to produce phenol. More information can be found in the Research Article by M. Sankaralingam and co-workers (DOI: 10.1002/cctc.202401645).

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封面专题:揭示镍(II)五齿配体配合物在芳香氧化中的催化活性(ChemCatChem 6/2025)
封面特征描述了在五齿酸镍催化剂和过氧化氢存在下苯羟基化成苯酚的过程。苯的C─H键的高度惰性表现为一个用锁链固定的球形笼。然而,强大的镍催化剂和氧化剂起到了关键作用,促进了其中一个C─H键的选择性氧化产生苯酚。更多信息可以在M. Sankaralingam及其同事的研究文章中找到(DOI: 10.1002/cctc.202401645)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
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