Modeling Acoustic Attenuation, Sound Velocity and Wave Propagation in Lithium-Ion Batteries via a Transfer Matrix

IF 4.7 4区 材料科学 Q2 ELECTROCHEMISTRY Batteries & Supercaps Pub Date : 2024-11-16 DOI:10.1002/batt.202400478
Simon Feiler, Dr. Lukas Gold, Dr. Sarah Hartmann, Dr. Guinevere A. Giffin
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Abstract

A simple 1D transfer matrix model of a battery is introduced and parametrized using harvested individual cell components at 0 % and 100 % SoC. This model allows for the calculation of group velocity and attenuation. The results of the model show good agreement with measured values, highlighting increased attenuation and group velocity at the resonances. This emphasizes the importance of selecting a suitable interrogation frequency for ultrasound investigations in lithium-ion batteries. The model accurately replicates the observed weakening of resonances with increasing SoC. Additionally, it provides the basis to fit US spectroscopy data in the future, enabling immediate determination of component thickness and the Young's modulus of individual components, along with aiding in the identification aging effects of the anode and cathode materials. The model can visualize wave propagation within the battery. At certain frequencies, standing waves form which could be used in high-intensity ultrasound applications targeted at individual cell components.

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通过传递矩阵模拟锂离子电池中的声衰减、声速和波传播
介绍了一种简单的电池一维传递矩阵模型,并使用在0%和100%荷电状态下收集的单个电池组件进行了参数化。该模型允许计算群速度和衰减。模型计算结果与实测值吻合较好,共振处的衰减和群速度增加。这强调了在锂离子电池的超声波调查中选择合适的询问频率的重要性。该模型准确地复制了观测到的共振随SoC增加而减弱的现象。此外,它为将来拟合美国光谱数据提供了基础,可以立即确定组件厚度和单个组件的杨氏模量,同时有助于识别阳极和阴极材料的老化效应。该模型可以可视化波在电池内的传播。在特定频率下,驻波可以用于针对单个细胞成分的高强度超声波应用。
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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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