{"title":"Photoelectrochemical Synthesis of Adipic Acid by Selective Oxidation of Cyclohexanone (Adv. Energy Mater. 11/2025)","authors":"Shanshan Zhang, Lan Luo, Jiangrong Yang, Wangsong Chen, Yucong Miao, Ruikang Zhang, Zhenhua Li, Rengui Li, Mingfei Shao, Xue Duan","doi":"10.1002/aenm.202570053","DOIUrl":null,"url":null,"abstract":"<p><b>Photoelectrochemical Syntheses</b></p><p>In article number 2405052, Ruikang Zhang, Zhenhua Li, Mingfei Shao, and co-workers first reported a photoelectrochemical strategy to achieve the selective oxidation of cyclohexanone to adipic acid using a cooperative Ni(OH)<sub>2</sub>/TiO<sub>2</sub> photoanode with H<sub>2</sub>O as oxygen source. The new Ni<sup>2+δ</sup>─OH* reactive center was in situ generated on a Ni(OH)<sub>2</sub>/TiO<sub>2</sub> photoanode under illumination, which significantly facilitates the activation of C<sub>α</sub>─H and the subsequent C─C cleavage to produce adipic acid.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 11","pages":""},"PeriodicalIF":26.0000,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570053","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Energy Materials","FirstCategoryId":"88","ListUrlMain":"https://advanced.onlinelibrary.wiley.com/doi/10.1002/aenm.202570053","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Photoelectrochemical Syntheses
In article number 2405052, Ruikang Zhang, Zhenhua Li, Mingfei Shao, and co-workers first reported a photoelectrochemical strategy to achieve the selective oxidation of cyclohexanone to adipic acid using a cooperative Ni(OH)2/TiO2 photoanode with H2O as oxygen source. The new Ni2+δ─OH* reactive center was in situ generated on a Ni(OH)2/TiO2 photoanode under illumination, which significantly facilitates the activation of Cα─H and the subsequent C─C cleavage to produce adipic acid.
期刊介绍：
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
