T. Sand, A. Rajagopal, M. Sattari, S. Bigdeli, M. Hättestrand, J.-E. Svensson, M. Halvarsson, L.-G. Johansson
{"title":"Nitridation of Three Austenitic Alloys at 1100 °C","authors":"T. Sand, A. Rajagopal, M. Sattari, S. Bigdeli, M. Hättestrand, J.-E. Svensson, M. Halvarsson, L.-G. Johansson","doi":"10.1007/s11085-025-10331-9","DOIUrl":null,"url":null,"abstract":"<div><p>The nitridation of three austenitic high-temperature alloys in 95% N<sub>2</sub> + 5% H<sub>2</sub> environment at 1100 °C was evaluated in terms of gravimetry and investigated by SEM–EDS, EPMA and STEM. Samples made from Alloy 600, 253 MA and 353 MA were exposed for 1 day, 1 week and 3 weeks. Alloy 600 underwent very little nitridation, while 253 MA and especially 353 MA, were heavily affected by nitride precipitation. The nitridation of all three alloys had reached equilibrium after three weeks; the extent of nitridation depending on the chromium activity in the alloy. The kinetics of nitrogen ingress into the alloy depends on nickel concentration, while the rate-determining step in the nitridation process is the nucleation and growth of the nitride precipitates.</p></div>","PeriodicalId":724,"journal":{"name":"Oxidation of Metals","volume":"102 2","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11085-025-10331-9.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Oxidation of Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11085-025-10331-9","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
The nitridation of three austenitic high-temperature alloys in 95% N2 + 5% H2 environment at 1100 °C was evaluated in terms of gravimetry and investigated by SEM–EDS, EPMA and STEM. Samples made from Alloy 600, 253 MA and 353 MA were exposed for 1 day, 1 week and 3 weeks. Alloy 600 underwent very little nitridation, while 253 MA and especially 353 MA, were heavily affected by nitride precipitation. The nitridation of all three alloys had reached equilibrium after three weeks; the extent of nitridation depending on the chromium activity in the alloy. The kinetics of nitrogen ingress into the alloy depends on nickel concentration, while the rate-determining step in the nitridation process is the nucleation and growth of the nitride precipitates.
期刊介绍：
Oxidation of Metals is the premier source for the rapid dissemination of current research on all aspects of the science of gas-solid reactions at temperatures greater than about 400˚C, with primary focus on the high-temperature corrosion of bulk and coated systems. This authoritative bi-monthly publishes original scientific papers on kinetics, mechanisms, studies of scales from structural and morphological viewpoints, transport properties in scales, phase-boundary reactions, and much more. Articles may discuss both theoretical and experimental work related to gas-solid reactions at the surface or near-surface of a material exposed to elevated temperatures, including reactions with oxygen, nitrogen, sulfur, carbon and halogens. In addition, Oxidation of Metals publishes the results of frontier research concerned with deposit-induced attack. Review papers and short technical notes are encouraged.
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