Harnessing interfacial engineering in covalent organic frameworks for lithium metal batteries

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Coordination Chemistry Reviews Pub Date : 2025-03-20 DOI:10.1016/j.ccr.2025.216604

Xiao-Meng Lu , Junaid Aslam , Muhammad Ahsan Waseem , Yifan Zhang , Weiwei Sun , Yong Wang

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Abstract

The application of lithium metal anodes (LMAs) in batteries promises high energy density but faces challenges due to uncontrollable Li dendrite formation and instability of the solid electrolyte interphase (SEI). The architectural features and diversity of fabrication methods of covalent organic frameworks (COFs), such as well-ordered pores, functionalities tunability, and remarkable stability, endow COF-based interfacial layers with homogenizing ion flux and accelerating ion transport, have demonstrated to be a straightforward and efficient way to tackle LMA problems. This review thoroughly reviews the general structure and linking modes of COFs, the Li⁺ interfacial chemistry and associated characteristics as well as the prominent progress occurring from 2019 to 2024. Meanwhile, this review attempts to propose some tactics anticipated in the future development of COFs for LMA applications in terms of large-scale manufacturing, improvement of battery performance, and exploration of the mechanism. It is widely believed that optimizing the synergistic effects between the building blocks of COFs will offer valuable insights and guidance for both researchers and practitioners working in this area.

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在锂金属电池共价有机框架中利用界面工程

锂金属阳极（LMAs）在电池中的应用有望实现高能量密度，但由于锂枝晶的不可控形成和固体电解质界面相（SEI）的不稳定性，面临着挑战。共价有机骨架（COFs）的结构特点和制备方法的多样性，如有序的孔隙、功能可调节性和显著的稳定性，赋予COFs基界面层均匀的离子通量和加速离子传输，已被证明是解决LMA问题的一种简单有效的方法。本文综述了COFs的一般结构和连接模式，Li+界面化学及其相关特征，以及2019 - 2024年的突出进展。同时，本文试图从规模化制造、电池性能提升、机理探索等方面提出未来COFs用于LMA应用的发展策略。人们普遍认为，优化COFs构建模块之间的协同效应将为这一领域的研究人员和实践者提供宝贵的见解和指导。

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来源期刊

Coordination Chemistry Reviews 化学-无机化学与核化学

CiteScore

34.30

自引率

5.30%

发文量

457

审稿时长

54 days

期刊介绍： Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.