Flower-like amorphous metal-organic-frameworks-based hybrid-solid-state electrolyte for high-performance lithium-metal battery.

Abstract

A flower-like porous amorphous Cu-aMOF-based SSE exhibits an ionic conductivity of 1.61 × 10^-3 S cm^-1 at 30 °C, a high lithium ion transference number of 0.71, and enables uniform Li deposition for 4000 h at 0.1 mA cm^-2, demonstrating excellent cycling and rate performance. Compared to traditional crystalline Cu-MOF (1.18 × 10^-3 S cm^-1, 0.46, 1900 h), it shows significant improvements, highlighting the potential of amorphous MOFs with continuous structures, abundant defects, and more active sites as novel electrolyte materials for high-performance lithium-metal batteries.