Layered Clay Confined Single-Atom Catalyst for Enhanced Radical Pathway to Achieve Ultrafast Degradation of Bisphenol A

Abstract

Seeking a technically promising method and cost-effective material to synthesize carrier-supported single-atom catalysts has attracted on-going research interests to overcome the low productivity and high costs for their industrial application. Montmorillonite (MT), a natural silicate clay mineral, has specific two-dimensional layered structure, and could be an excellent carrier, which creates a unique microenvironment to enhance molecule adsorption and interfacial reactions within the single atoms, free radicals and pollutants in the heterogeneous catalytic system. We synthesized cobalt single-atom catalyst (Co-SAC) by ball milling MT and cobalt salt using surface and spatial confinement strategy. Co-SAC/MT catalyst was used to activate peroxymonosulfate for degrading emerging contaminants bisphenol A (BPA). Characterization results revealed that Co single atoms were confined in the interlayer of MT as Co-O₆-Si. Co-SAC/MT catalyst demonstrated remarkable molecular interaction capabilities to shorten mass transfer distance of free radical diffusion to the target pollutants, enhance the utilization rate of free radicals, and thus improve the efficiency of oxidation reaction. The BPA solution was completely degraded in 3 min, with a mineralization rate of 75.7% in 10 min. This study provides a simple and efficient method for the preparation of single-atom catalysts, which is expected to achieve large-scale production of single-atom catalysts.