Heng-Tong Bu, Jia-Lun Gu, Yun-Shuai Su, Yang Shao, Ke-Fu Yao
{"title":"Achieving ultrahigh-specific strength and enhanced GFA in Ti-based bulk metallic glasses via a two-step alloying strategy","authors":"Heng-Tong Bu, Jia-Lun Gu, Yun-Shuai Su, Yang Shao, Ke-Fu Yao","doi":"10.1007/s12598-024-03036-6","DOIUrl":null,"url":null,"abstract":"<div><p>Ti-based bulk metallic glasses (BMGs) have attracted increasing attention due to their high specific strength. However, a fundamental conflict exists between the specific strength and glass-forming ability (GFA) of Ti-based BMGs, restricting their commercial applications significantly. In this study, this challenge was addressed by introducing a two-step alloying strategy to mitigate the remarkable density increment effect associated with heavy alloying elements required for enhancing the GFA. Consequently, through two-step alloying with Al and Fe in sequence, simultaneous enhancements in specific strength and GFA were achieved based on a Ti–Zr–Be ternary metallic glass, resulting in the development of a series of centimeter-sized metallic glasses exhibiting ultrahigh-specific strength. Notably, the newly developed (Ti<sub>45</sub>Zr<sub>20</sub>Be<sub>31</sub>Al<sub>4</sub>)<sub>94</sub>Fe<sub>6</sub> alloy established a new record for the specific strength of Ti-based BMGs. Along with a critical diameter (<i>D</i><sub>c</sub>) of 10 mm, it offers the optimal scheme for balancing the specific strength and GFA of Ti-based BMGs. The present results further brighten the application prospects of Ti-based BMGs as lightweight materials.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 3","pages":"1932 - 1942"},"PeriodicalIF":9.6000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Rare Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12598-024-03036-6","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Ti-based bulk metallic glasses (BMGs) have attracted increasing attention due to their high specific strength. However, a fundamental conflict exists between the specific strength and glass-forming ability (GFA) of Ti-based BMGs, restricting their commercial applications significantly. In this study, this challenge was addressed by introducing a two-step alloying strategy to mitigate the remarkable density increment effect associated with heavy alloying elements required for enhancing the GFA. Consequently, through two-step alloying with Al and Fe in sequence, simultaneous enhancements in specific strength and GFA were achieved based on a Ti–Zr–Be ternary metallic glass, resulting in the development of a series of centimeter-sized metallic glasses exhibiting ultrahigh-specific strength. Notably, the newly developed (Ti45Zr20Be31Al4)94Fe6 alloy established a new record for the specific strength of Ti-based BMGs. Along with a critical diameter (Dc) of 10 mm, it offers the optimal scheme for balancing the specific strength and GFA of Ti-based BMGs. The present results further brighten the application prospects of Ti-based BMGs as lightweight materials.
期刊介绍:
Rare Metals is a monthly peer-reviewed journal published by the Nonferrous Metals Society of China. It serves as a platform for engineers and scientists to communicate and disseminate original research articles in the field of rare metals. The journal focuses on a wide range of topics including metallurgy, processing, and determination of rare metals. Additionally, it showcases the application of rare metals in advanced materials such as superconductors, semiconductors, composites, and ceramics.