Anjali Depala , Manon T. Lachmann , Simone Morra , James A. Birrell , Patricia Rodríguez-Maciá
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引用次数: 0
Abstract
[FeFe]-hydrogenases are highly-active hydrogen-conversion biocatalysts using Earth-abundant metals in their active-site. Understanding their mechanism may enable design of catalysts for renewable energy storage. Here, observation of the crucial Fe-hydride-containing (Hhyd) intermediate in a PDT-variant of [FeFe]-hydrogenase reveals deeper insight into the role of the dithiolate bridgehead in the catalytic mechanism.
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