Sanicro 25 in advanced ultra-supercritical (AUSC) steam: Oxidation behaviour of a high strength, heat-resistant austenitic stainless steel for high-efficiency coal-fired power plants

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-07-01 Epub Date: 2025-03-19 DOI:10.1016/j.corsci.2025.112878
C. Sundaresan , Bhagwat Ghule , Kamanio Chattopadhyay , V.S. Raja
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Abstract

The oxidation behaviour of Sanicro 25 was investigated in advanced ultra-supercritical (AUSC) steam at 650–710 ℃, 31 MPa for 600 h. The alloy recorded low weight gains and formed sub-micron-sized external oxide comprising (Mn,Fe,Ni)Cr2O4 spinel over Cr2O3. Its oxidation resistance was better than other candidate heat-resistant stainless steels and on par with Ni-base superalloy 617. Fine strengthening precipitates of Cu, Cr-rich M23C6, W-rich Lave’s and Nb-rich Z phases were found to form in the substrate during oxidation and their volume fraction increased with increasing temperature. The reasons for the alloy’s superior AUSC steam oxidation behaviour and its implications are discussed.
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先进超超临界(AUSC)蒸汽中的Sanicro 25:用于高效燃煤电厂的高强度耐热奥氏体不锈钢的氧化行为
研究了Sanicro 25在650 ~ 710℃、31 MPa、600 h的超超临界(AUSC)蒸汽中的氧化行为。该合金的增重较低,形成了亚微米级的外部氧化物,由(Mn,Fe,Ni)Cr2O4尖晶石覆盖在Cr2O3上。其抗氧化性能优于其他候选耐热不锈钢,与镍基高温合金617相当。在氧化过程中,基体中形成了Cu相、富cr相M23C6相、富w相Lave’s相和富nb相的细小强化相,其体积分数随温度升高而增大。讨论了该合金具有优异的AUSC蒸汽氧化性能的原因及其意义。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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