Novel dual-phase Ce0.8Gd0.2O2−δ – Gd1-xCexFe1-yCoyO3 composite oxygen transport membrane

IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Open Ceramics Pub Date : 2025-06-01 Epub Date: 2025-03-17 DOI:10.1016/j.oceram.2025.100771
Liudmila Fischer , Nawar Haddad , Ke Ran , Stefan Baumann , Doris Sebold , Joachim Mayer , Jürgen Dornseiffer , Arian Nijmeijer , Olivier Guillon , Wilhelm A. Meulenberg
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Abstract

Oxygen Transport Membranes with mixed oxygen ionic-electronic conductivity are investigated for in-situ oxygen separation in various processes such as oxy-combustion or catalytic membrane reactors enabling process intensification. Dual-phase composite membranes are of high interest due to the opportunity selecting thermo-chemical stable phases conducting oxygen ions and electrons separately. Recently, we reported a novel composite utilizing a donor doped gadolinium ferrite Gd0.85Ce0.15Fe0.75Co0.25O3 as electronic conductor. Here, the composition of this perovskite system is systematically varied and its structural as well as functional properties are investigated. Moreover, the option of a cobalt-free composition is investigated.

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新型双相Ce0.8Gd0.2O2−δ - Gd1-xCexFe1-yCoyO3复合输氧膜
研究了具有混合氧离子-电子电导率的氧传输膜在各种过程中的原位氧分离,如氧燃烧或催化膜反应器,使过程增强。双相复合膜由于有机会选择热化学稳定相分别导电氧离子和电子而受到高度关注。最近,我们报道了一种利用供体掺杂钆铁氧体Gd0.85Ce0.15Fe0.75Co0.25O3作为电子导体的新型复合材料。本文系统地研究了钙钛矿体系的组成,并对其结构和功能特性进行了研究。此外,还研究了无钴组合物的选择。
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来源期刊
Open Ceramics
Open Ceramics Materials Science-Materials Chemistry
CiteScore
4.20
自引率
0.00%
发文量
102
审稿时长
67 days
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