首页 > 最新文献

Open Ceramics最新文献

英文 中文
Recyclability of ceramic powder in CerAM vat photopolymerization 陶瓷粉末在CerAM还原光聚合中的可回收性
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2026-01-02 DOI: 10.1016/j.oceram.2026.100908
Matilde Aronne , Eric Schwarzer-Fischer , Alberto Ballesio , Nadine Lorenz , Valentina Bertana , Uwe Scheithauer , Sergio Ferrero , Luciano Scaltrito
The sustainability of the manufacturing industry is becoming an increasingly hot topic, particularly the reintroduction of waste into the production chain. The use of AM of ceramics can reduce waste and enable complex, lightweight designs, however, practical routes to circularity remain underdeveloped. This investigation aims to explore the potential of coupling these additive fabrication techniques with raw materials from alternative sources of ceramics, such as printing wastes and error prints, developing a photocurable ceramic suspension for DLP technology. For resin preparation, a polymeric premix was first prepared by combining a mixture of different acrylate monomers as a photoreactive binder with a non-reactive plasticizing additive. Alumina was recovered from failed green bodies following matrix burning out, parts grinding and sieving of the obtained powder. Subsequent investigations of the powder by SEM imaging and EDX analysis were carried out to verify particle morphology and average dimensions and to identify any contaminants in the recycled material. The suspension viscosity and curing behaviour were measured. Finally, the mechanical characteristics of printed parts, their density, their shrinkage, as well as possible contaminants, were evaluated, in order to understand the impact of the recycling process on material performances and to determine its possible application fields. Tests results provided a practical recycling potential for alumina in DLP, offering viable solutions in facilitating closed-loop CerAM manufacturing.
制造业的可持续性正在成为一个越来越热门的话题,特别是将废物重新引入生产链。陶瓷增材制造的使用可以减少浪费,实现复杂、轻量化的设计,然而,实现循环的实际途径仍然不发达。本研究旨在探索将这些增材制造技术与其他陶瓷原料(如印刷废料和错误打印)相结合的潜力,开发用于DLP技术的光固化陶瓷悬浮液。对于树脂制备,首先通过将不同丙烯酸酯单体的混合物作为光反应性粘合剂与非反应性增塑剂相结合来制备聚合物预混料。氧化铝是从失败的绿体中回收的,经过基体烧坏、零件研磨和所得粉末的筛分。随后通过SEM成像和EDX分析对粉末进行了调查,以验证颗粒形态和平均尺寸,并确定回收材料中的任何污染物。测定了悬浮液粘度和固化性能。最后,对打印部件的机械特性、密度、收缩率以及可能的污染物进行了评估,以了解回收过程对材料性能的影响,并确定其可能的应用领域。测试结果提供了氧化铝在DLP中的实际回收潜力,为促进闭环CerAM制造提供了可行的解决方案。
{"title":"Recyclability of ceramic powder in CerAM vat photopolymerization","authors":"Matilde Aronne ,&nbsp;Eric Schwarzer-Fischer ,&nbsp;Alberto Ballesio ,&nbsp;Nadine Lorenz ,&nbsp;Valentina Bertana ,&nbsp;Uwe Scheithauer ,&nbsp;Sergio Ferrero ,&nbsp;Luciano Scaltrito","doi":"10.1016/j.oceram.2026.100908","DOIUrl":"10.1016/j.oceram.2026.100908","url":null,"abstract":"<div><div>The sustainability of the manufacturing industry is becoming an increasingly hot topic, particularly the reintroduction of waste into the production chain. The use of AM of ceramics can reduce waste and enable complex, lightweight designs, however, practical routes to circularity remain underdeveloped. This investigation aims to explore the potential of coupling these additive fabrication techniques with raw materials from alternative sources of ceramics, such as printing wastes and error prints, developing a photocurable ceramic suspension for DLP technology. For resin preparation, a polymeric premix was first prepared by combining a mixture of different acrylate monomers as a photoreactive binder with a non-reactive plasticizing additive. Alumina was recovered from failed green bodies following matrix burning out, parts grinding and sieving of the obtained powder. Subsequent investigations of the powder by SEM imaging and EDX analysis were carried out to verify particle morphology and average dimensions and to identify any contaminants in the recycled material. The suspension viscosity and curing behaviour were measured. Finally, the mechanical characteristics of printed parts, their density, their shrinkage, as well as possible contaminants, were evaluated, in order to understand the impact of the recycling process on material performances and to determine its possible application fields. Tests results provided a practical recycling potential for alumina in DLP, offering viable solutions in facilitating closed-loop CerAM manufacturing.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100908"},"PeriodicalIF":2.8,"publicationDate":"2026-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring calcination parameters: Impacts on reaction kinetics, mechanical strength, and microstructural evolution in laterite-derived geopolymers 探索煅烧参数:对红土衍生地聚合物反应动力学、机械强度和微观结构演变的影响
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-31 DOI: 10.1016/j.oceram.2025.100907
Rodrigue Cyriaque Kaze , Özgür Cengiz , Abdolhossein Naghizadeh , Hakan Gungunes , Gisèle Laure Lecomte-Nana , Chaouche Mohend
Calcined laterite offers a promising alternative to traditional precursors in geopolymer synthesis. Despite its potential, knowledge regarding the effects of calcination conditions, particularly the heating rate, on its properties remains sparse. This research delved into the impact of different calcination heating rates on laterite and the subsequent geopolymer products by calcining laterite at 600°C for 4 hours, with heating rates ranging from 1.5 to 10°C/min. Analytical techniques including isothermal conduction calorimetry (ICC), setting time determination, XRD, TG/DTA, XF, FTIR, Mössbauer spectroscopy and SEM/EDS were employed to characterize both raw and calcined laterite as well as the resulting geopolymer products.
Key findings indicate that higher heating rates augment the amorphous phase in the precursors, leading to decreased setting times. This reduction is directly associated with heightened reaction activity and increased heat release, as noted from ICC results. Notably, mechanical properties improved at a heating rate of 7.5°C/min, giving a compressive strength of 51 MPa. The mentioned heating rate also resulted in the best porosity and water absorption values of 14 % and 8 %, respectively, suggestive of a more consolidated microstructure. The data ultimately designates 7.5°C/min as the optimal heating rate for crafting geopolymers with superior mechanical and microstructural attributes. Mössbauer spectroscopy revealed details of the iron site geometry and oxidation state, showing an increase in Fe3+ content within the silicoaluminate phases. This effect was slightly more pronounced in samples synthesised with a heating rate of 7.5°C/min.
煅烧红土是一种很有前途的替代传统的地聚合物前驱体的合成方法。尽管它具有潜力,但关于煅烧条件,特别是加热速率对其性能的影响的知识仍然很少。本研究通过红土在600℃下煅烧4小时,升温速率为1.5 ~ 10℃/min,研究了不同的煅烧升温速率对红土及其后续地聚合物产品的影响。采用等温传导量热法(ICC)、凝固时间测定、XRD、TG/DTA、XF、FTIR、Mössbauer光谱和SEM/EDS等分析技术对原料和煅烧红土及其产物进行了表征。关键发现表明,较高的加热速率增加了前驱体中的非晶相,导致凝结时间缩短。从ICC的结果中可以看出,这种减少与反应活性的增强和热量释放的增加直接相关。值得注意的是,当升温速率为7.5°C/min时,其力学性能得到改善,抗压强度达到51 MPa。在上述加热速率下,孔隙率和吸水率分别达到14%和8%,表明微观结构更加固结。数据最终指定7.5°C/min为制作具有优越机械和微观结构属性的地聚合物的最佳加热速率。Mössbauer光谱揭示了铁位点几何形状和氧化状态的细节,表明在硅铝酸盐相中Fe3+含量增加。在升温速率为7.5°C/min的样品中,这种效果稍微明显一些。
{"title":"Exploring calcination parameters: Impacts on reaction kinetics, mechanical strength, and microstructural evolution in laterite-derived geopolymers","authors":"Rodrigue Cyriaque Kaze ,&nbsp;Özgür Cengiz ,&nbsp;Abdolhossein Naghizadeh ,&nbsp;Hakan Gungunes ,&nbsp;Gisèle Laure Lecomte-Nana ,&nbsp;Chaouche Mohend","doi":"10.1016/j.oceram.2025.100907","DOIUrl":"10.1016/j.oceram.2025.100907","url":null,"abstract":"<div><div>Calcined laterite offers a promising alternative to traditional precursors in geopolymer synthesis. Despite its potential, knowledge regarding the effects of calcination conditions, particularly the heating rate, on its properties remains sparse. This research delved into the impact of different calcination heating rates on laterite and the subsequent geopolymer products by calcining laterite at 600°C for 4 hours, with heating rates ranging from 1.5 to 10°C/min. Analytical techniques including isothermal conduction calorimetry (ICC), setting time determination, XRD, TG/DTA, XF, FTIR, Mössbauer spectroscopy and SEM/EDS were employed to characterize both raw and calcined laterite as well as the resulting geopolymer products.</div><div>Key findings indicate that higher heating rates augment the amorphous phase in the precursors, leading to decreased setting times. This reduction is directly associated with heightened reaction activity and increased heat release, as noted from ICC results. Notably, mechanical properties improved at a heating rate of 7.5°C/min, giving a compressive strength of 51 MPa. The mentioned heating rate also resulted in the best porosity and water absorption values of 14 % and 8 %, respectively, suggestive of a more consolidated microstructure. The data ultimately designates 7.5°C/min as the optimal heating rate for crafting geopolymers with superior mechanical and microstructural attributes. Mössbauer spectroscopy revealed details of the iron site geometry and oxidation state, showing an increase in Fe<sup>3+</sup> content within the silicoaluminate phases. This effect was slightly more pronounced in samples synthesised with a heating rate of 7.5°C/min.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100907"},"PeriodicalIF":2.8,"publicationDate":"2025-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145976250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and characterization of eco-friendly CaO-modified cellulose acetate fibers via electrospinning for potential biomedical applications 静电纺丝法制备和表征生态友好型草酸改性醋酸纤维素纤维的潜在生物医学应用
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-28 DOI: 10.1016/j.oceram.2025.100906
Wasan Alkaron , Tamás Kolonits , Katalin Balázsi , Csaba Balázsi
New eco-friendly fiber composites were developed by electrospinning cellulose acetate (CA) combined with calcium oxide (CaO) derived from thermally treated waste eggshells. CA solutions were prepared at varying concentrations to optimize the ideal concentration for producing smooth, continuous, and beads-free fibers. Various amounts of CaO were then added to assess its impact on fiber structure, crystallinity, and swelling characteristics.
FTIR examinations demonstrated that CaO was effectively integrated without altering the CA structure, however XRD investigations revealed reduction in crystallinity with increasing CaO content. The swelling capacity remarkedly increased to 710% at 4% CaO, attributed to enhanced porosity and hydrophilicity, before showing a slight decline at higher concentrations due to particle aggregation. These results highlight a sustainable method for producing functional CA/CaO composites with tailored properties for promising applications in biomedical and environmental fields. Our further aim is to study the biocompatibility, cytotoxicity and the photocatalytic activity of the prepared composites.
以经热处理的废蛋壳为原料,采用静电纺丝法将醋酸纤维素(CA)与氧化钙(CaO)结合,制备了新型环保纤维复合材料。制备了不同浓度的CA溶液,以优化生产光滑、连续和无珠纤维的理想浓度。然后加入不同量的CaO来评估其对纤维结构、结晶度和膨胀特性的影响。FTIR测试表明,在不改变CA结构的情况下,CaO被有效地整合,但XRD研究表明,随着CaO含量的增加,结晶度降低。在CaO浓度为4%时,由于孔隙度和亲水性增强,溶胀率再次显著增加至710%,而在较高浓度时,由于颗粒聚集,溶胀率略有下降。这些结果强调了一种可持续的方法来生产具有定制性能的功能性CA/CaO复合材料,在生物医学和环境领域具有广阔的应用前景。我们进一步的目的是研究制备的复合材料的生物相容性、细胞毒性和光催化活性。
{"title":"Fabrication and characterization of eco-friendly CaO-modified cellulose acetate fibers via electrospinning for potential biomedical applications","authors":"Wasan Alkaron ,&nbsp;Tamás Kolonits ,&nbsp;Katalin Balázsi ,&nbsp;Csaba Balázsi","doi":"10.1016/j.oceram.2025.100906","DOIUrl":"10.1016/j.oceram.2025.100906","url":null,"abstract":"<div><div>New eco-friendly fiber composites were developed by electrospinning cellulose acetate (CA) combined with calcium oxide (CaO) derived from thermally treated waste eggshells. CA solutions were prepared at varying concentrations to optimize the ideal concentration for producing smooth, continuous, and beads-free fibers. Various amounts of CaO were then added to assess its impact on fiber structure, crystallinity, and swelling characteristics.</div><div>FTIR examinations demonstrated that CaO was effectively integrated without altering the CA structure, however XRD investigations revealed reduction in crystallinity with increasing CaO content. The swelling capacity remarkedly increased to 710% at 4% CaO, attributed to enhanced porosity and hydrophilicity, before showing a slight decline at higher concentrations due to particle aggregation. These results highlight a sustainable method for producing functional CA/CaO composites with tailored properties for promising applications in biomedical and environmental fields. Our further aim is to study the biocompatibility, cytotoxicity and the photocatalytic activity of the prepared composites.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100906"},"PeriodicalIF":2.8,"publicationDate":"2025-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145883435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring Ce distribution via precursor engineering in spray pyrolyzed Ce-doped bioactive glass: Insights into bioactivity, cytotoxicity, and antibacterial characteristics in vitro 通过前体工程在喷雾热解Ce掺杂生物活性玻璃中调整Ce分布:对生物活性、细胞毒性和体外抗菌特性的见解
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-22 DOI: 10.1016/j.oceram.2025.100903
Sudharshan PG, Yu-Hsiang Chen, Yu-Jen Chou
Bioactive glass (BG) has gained attention for its biocompatible, non-toxic nature in addressing bone defects. One of the limitations is the absence of antibacterial characteristics, which could be addressed through the incorporation of Ce, as it is known to exhibit antibacterial properties. In this study, BG specimens doped with 10 mol% of Ce with three Ce precursors were synthesized via the spray pyrolysis to control the distribution of Ce. Employing X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), the specimens were analyzed on their phase characteristics, particle morphology, inner structure, and elemental distribution. The results demonstrated that both undoped and Ce-doped possess a smooth spherical morphology. Meanwhile, the cross-sectional samples revealed CeN-treated and CeAN-treated specimens led to homogeneous Ce distributions, whereas CeA-treated BG resulted in pronounced Ce segregation on the surface. These differences are attributed to precursor-specific dissolution and migration behavior during synthesis. These distinct Ce distributions influenced their bioactivity, cytotoxicity, and antibacterial characteristics, with CeA-treated specimens demonstrating the highest antibacterial efficiency (94.5 ± 1.32%) against Escherichia coli, and the highest cell viability (105.31 ± 2.78) as compared to the CeN and CeAN-treated specimens.
生物活性玻璃(BG)因其具有生物相容性和无毒性而受到关注。其中一个限制是缺乏抗菌特性,这可以通过掺入Ce来解决,因为已知Ce具有抗菌特性。为了控制Ce的分布,本研究采用喷雾热解法制备了掺量为10 mol% Ce的BG样品和三种Ce前驱体。采用x射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对样品的物相特征、颗粒形貌、内部结构和元素分布进行了分析。结果表明,未掺杂和掺铈均具有光滑的球形形貌。同时,横断面样品显示,cen处理和cean处理的样品表面Ce分布均匀,而cea处理的BG表面Ce偏析明显。这些差异归因于合成过程中前体特异性溶解和迁移行为。这些不同的Ce分布影响了它们的生物活性、细胞毒性和抗菌特性,与CeN和cean处理的样品相比,cea处理的样品对大肠杆菌的抗菌效率最高(94.5±1.32%),细胞活力最高(105.31±2.78)。
{"title":"Tailoring Ce distribution via precursor engineering in spray pyrolyzed Ce-doped bioactive glass: Insights into bioactivity, cytotoxicity, and antibacterial characteristics in vitro","authors":"Sudharshan PG,&nbsp;Yu-Hsiang Chen,&nbsp;Yu-Jen Chou","doi":"10.1016/j.oceram.2025.100903","DOIUrl":"10.1016/j.oceram.2025.100903","url":null,"abstract":"<div><div>Bioactive glass (BG) has gained attention for its biocompatible, non-toxic nature in addressing bone defects. One of the limitations is the absence of antibacterial characteristics, which could be addressed through the incorporation of Ce, as it is known to exhibit antibacterial properties. In this study, BG specimens doped with 10 mol% of Ce with three Ce precursors were synthesized via the spray pyrolysis to control the distribution of Ce. Employing X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), the specimens were analyzed on their phase characteristics, particle morphology, inner structure, and elemental distribution. The results demonstrated that both undoped and Ce-doped possess a smooth spherical morphology. Meanwhile, the cross-sectional samples revealed CeN-treated and CeAN-treated specimens led to homogeneous Ce distributions, whereas CeA-treated BG resulted in pronounced Ce segregation on the surface. These differences are attributed to precursor-specific dissolution and migration behavior during synthesis. These distinct Ce distributions influenced their bioactivity, cytotoxicity, and antibacterial characteristics, with CeA-treated specimens demonstrating the highest antibacterial efficiency (94.5 ± 1.32%) against <em>Escherichia coli,</em> and the highest cell viability (105.31 ± 2.78) as compared to the CeN and CeAN-treated specimens.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100903"},"PeriodicalIF":2.8,"publicationDate":"2025-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145839505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of the rheological behavior of polycaprolactone-borosilicate hybrid compositions on the electrospinning fibers' performance 聚己内酯-硼硅酸盐杂化组合物流变行为对静电纺丝纤维性能的影响
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-22 DOI: 10.1016/j.oceram.2025.100904
Soraia A.R. Coelho , Rodrigo Moreno , Maria Helena Vaz Fernandes , José Carlos Almeida
The successful electrospinning of hybrid sol-gel organic-inorganic fibers is challenging, as it relies on the viscosity and temporal stability of the precursor solution. In sol-gel, ongoing hydrolysis-condensation reactions continuously modify rheology, thereby influencing fiber diameter and morphology. To address this, two distinct sol-gel protocols (P1 and P2) were developed by varying water, acid, solvent, and concentration levels to tune crosslinking kinetics. The protocols exhibited different stability profiles and processing windows, resulting in class I hybrids with tailored morphologies. P1 provided a longer 6-hour processing window, yielding porous membranes with larger fibers (∼500 nm), while P2 produced denser membranes with smaller fibers (∼100 nm) within a 2-hour window. These findings demonstrate that adjusting sol-gel chemistry offers a powerful approach to control crosslinking degree and membrane morphology within the same hybrid system. This tunability expands the potential of these membranes for diverse tissue engineering applications, including scaffolds designed to match the distinct structural requirements.
成功的静电纺丝混合溶胶-凝胶有机-无机纤维具有挑战性,因为它依赖于前驱体溶液的粘度和时间稳定性。在溶胶-凝胶中,持续进行的水解-缩合反应不断地改变流变性,从而影响纤维的直径和形态。为了解决这个问题,通过改变水、酸、溶剂和浓度水平来调整交联动力学,开发了两种不同的溶胶-凝胶方案(P1和P2)。这些方案具有不同的稳定性概况和处理窗口,从而产生具有定制形态的I类杂交种。P1提供了更长的6小时加工窗口,产生了具有较大纤维(~ 500 nm)的多孔膜,而P2在2小时窗口内产生了具有较小纤维(~ 100 nm)的致密膜。这些发现表明,调节溶胶-凝胶化学为控制同一杂化体系内的交联度和膜形态提供了一种强有力的方法。这种可调节性扩大了这些膜在各种组织工程应用中的潜力,包括为满足不同结构要求而设计的支架。
{"title":"Influence of the rheological behavior of polycaprolactone-borosilicate hybrid compositions on the electrospinning fibers' performance","authors":"Soraia A.R. Coelho ,&nbsp;Rodrigo Moreno ,&nbsp;Maria Helena Vaz Fernandes ,&nbsp;José Carlos Almeida","doi":"10.1016/j.oceram.2025.100904","DOIUrl":"10.1016/j.oceram.2025.100904","url":null,"abstract":"<div><div>The successful electrospinning of hybrid sol-gel organic-inorganic fibers is challenging, as it relies on the viscosity and temporal stability of the precursor solution. In sol-gel, ongoing hydrolysis-condensation reactions continuously modify rheology, thereby influencing fiber diameter and morphology. To address this, two distinct sol-gel protocols (P1 and P2) were developed by varying water, acid, solvent, and concentration levels to tune crosslinking kinetics. The protocols exhibited different stability profiles and processing windows, resulting in class I hybrids with tailored morphologies. P1 provided a longer 6-hour processing window, yielding porous membranes with larger fibers (∼500 nm), while P2 produced denser membranes with smaller fibers (∼100 nm) within a 2-hour window. These findings demonstrate that adjusting sol-gel chemistry offers a powerful approach to control crosslinking degree and membrane morphology within the same hybrid system. This tunability expands the potential of these membranes for diverse tissue engineering applications, including scaffolds designed to match the distinct structural requirements.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100904"},"PeriodicalIF":2.8,"publicationDate":"2025-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145883259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of recycled fired clay brick as a supplement in an acidic environment to create geopolymer materials based on volcanic ash 利用回收的烧制粘土砖作为补充,在酸性环境中创造基于火山灰的地聚合物材料
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-19 DOI: 10.1016/j.oceram.2025.100902
Gabriel A. Tchamabo , Hamed I. Riyap , Aimard M.N. Moudio , Charles Banenzoué , Daniel. J.D. Dina
This work aimed to assess how recycled fired clay brick affects the physical, microstructural and compressive strengths of volcanic ash based geopolymer materials made in an acidic environment. The volcanic ash was substituted with 0, 10, 20, 30 and 40 wt. % of recycled fired clay brick powder. A phosphoric acid solution with a molarity of 10 M is utilised as hardener. When the amount of recycled fired clay brick is increased from 0 to 40 wt. %, the compressive strengths of the geopolymer materials rise from 23.19 to 62.22 MPa, water absorption and porosity decrease from 7.73 to 5.96 % and from 13.66 to 11.61 %, respectively. The compact and dense microstructures can be observed on the micrographies of the acid-based geopolymer materials. It can be concluded that incorporation of recycled bricks into volcanic ash improves cohesion between the two aluminosilicate sources in the presence of phosphoric acid, resulting in higher compressive strength of acid-based geopolymers.
这项工作旨在评估再生烧制粘土砖如何影响酸性环境下火山灰基地聚合物材料的物理、微观结构和抗压强度。用0、10、20、30和40 wt %的再生烧制粘土砖粉代替火山灰。使用摩尔浓度为10 M的磷酸溶液作为硬化剂。当再生烧制粘土砖的掺量从0 wt. %增加到40 wt. %时,地聚合物材料的抗压强度从23.19 MPa增加到62.22 MPa,吸水率和孔隙率分别从7.73%和13.66%降低到5.96%和11.61%。在酸基地聚合物材料的显微照片上可以观察到致密的微观结构。由此可以得出结论,在磷酸存在的情况下,将再生砖掺入火山灰中可以改善两种铝硅酸盐源之间的粘聚性,从而提高酸基地聚合物的抗压强度。
{"title":"Utilization of recycled fired clay brick as a supplement in an acidic environment to create geopolymer materials based on volcanic ash","authors":"Gabriel A. Tchamabo ,&nbsp;Hamed I. Riyap ,&nbsp;Aimard M.N. Moudio ,&nbsp;Charles Banenzoué ,&nbsp;Daniel. J.D. Dina","doi":"10.1016/j.oceram.2025.100902","DOIUrl":"10.1016/j.oceram.2025.100902","url":null,"abstract":"<div><div>This work aimed to assess how recycled fired clay brick affects the physical, microstructural and compressive strengths of volcanic ash based geopolymer materials made in an acidic environment. The volcanic ash was substituted with 0, 10, 20, 30 and 40 wt. % of recycled fired clay brick powder. A phosphoric acid solution with a molarity of 10 M is utilised as hardener. When the amount of recycled fired clay brick is increased from 0 to 40 wt. %, the compressive strengths of the geopolymer materials rise from 23.19 to 62.22 MPa, water absorption and porosity decrease from 7.73 to 5.96 % and from 13.66 to 11.61 %, respectively. The compact and dense microstructures can be observed on the micrographies of the acid-based geopolymer materials. It can be concluded that incorporation of recycled bricks into volcanic ash improves cohesion between the two aluminosilicate sources in the presence of phosphoric acid, resulting in higher compressive strength of acid-based geopolymers.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100902"},"PeriodicalIF":2.8,"publicationDate":"2025-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145925226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of different morphologies of ZnO using different types of organic modifiers for the enhancement of catalytic activity 采用不同类型的有机改性剂合成不同形貌的ZnO以增强催化活性
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-19 DOI: 10.1016/j.oceram.2025.100901
Md. Atikur Rahman , Tasnimul Quader Tazim , Samiur Rahman , Md. Tanvir Hossain , Muhammad Shahriar Bashar , Dipa Islam , Samina Ahmed , Md. Sahadat Hossain
This study investigates the effect of different organic modifiers, such as urea, ethylene glycol, a urea–ethylene glycol mixture, citric acid, and ammonium hydroxide, on the morphology and characteristics of ZnO nanoparticles synthesized via the hydrothermal method. Structural and optical characterizations were conducted utilizing XRD, FTIR, FESEM, and UV–Vis spectroscopy, demonstrating that the incorporation of these modifiers not only regulated particle size and morphology but also modified crystallinity and associated crystallographic attributes. Different morphologies such as, nanosheets (thickness ∼110 nm) with urea, spherical nanoparticles (∼90 nm) with ethylene glycol, nanosheets with surface imperfections (∼41 nm) with urea-ethylene glycol mixture, flower-like structures with citric acid, and nanorods (∼640 nm) with ammonium hydroxide, were produced. The crystallite sizes determined using the Scherrer equation range between 21.38 nm to 47.17 nm. The photocatalytic activity of the modified ZnO nanoparticles, evaluated from their degradation percentages, ranged from a minimum of 58.92% to a maximum of 94.80%. The findings emphasize the importance of organic modifiers in modifying the morphology, crystallinity, and photocatalytic effectiveness of ZnO nanoparticles, providing useful insights for creating new photocatalysts with excellent performance.
本研究考察了尿素、乙二醇、尿素-乙二醇混合物、柠檬酸和氢氧化铵等不同有机改性剂对水热法制备ZnO纳米粒子形貌和性能的影响。利用XRD, FTIR, FESEM和UV-Vis光谱进行了结构和光学表征,表明这些改性剂的加入不仅可以调节颗粒大小和形貌,还可以改变结晶度和相关的晶体学属性。不同的形貌,如尿素纳米片(厚度~ 110 nm),乙二醇球形纳米颗粒(~ 90 nm),尿素-乙二醇混合物的表面缺陷纳米片(~ 41 nm),柠檬酸的花状结构和氢氧化铵的纳米棒(~ 640 nm),生产出来。利用Scherrer方程确定的晶体尺寸范围在21.38 ~ 47.17 nm之间。改性ZnO纳米粒子的光催化活性从最小的58.92%到最大的94.80%不等。该研究结果强调了有机改性剂在改变ZnO纳米颗粒的形貌、结晶度和光催化效能方面的重要性,为开发具有优异性能的新型光催化剂提供了有用的见解。
{"title":"Synthesis of different morphologies of ZnO using different types of organic modifiers for the enhancement of catalytic activity","authors":"Md. Atikur Rahman ,&nbsp;Tasnimul Quader Tazim ,&nbsp;Samiur Rahman ,&nbsp;Md. Tanvir Hossain ,&nbsp;Muhammad Shahriar Bashar ,&nbsp;Dipa Islam ,&nbsp;Samina Ahmed ,&nbsp;Md. Sahadat Hossain","doi":"10.1016/j.oceram.2025.100901","DOIUrl":"10.1016/j.oceram.2025.100901","url":null,"abstract":"<div><div>This study investigates the effect of different organic modifiers, such as urea, ethylene glycol, a urea–ethylene glycol mixture, citric acid, and ammonium hydroxide, on the morphology and characteristics of ZnO nanoparticles synthesized via the hydrothermal method. Structural and optical characterizations were conducted utilizing XRD, FTIR, FESEM, and UV–Vis spectroscopy, demonstrating that the incorporation of these modifiers not only regulated particle size and morphology but also modified crystallinity and associated crystallographic attributes. Different morphologies such as, nanosheets (thickness ∼110 nm) with urea, spherical nanoparticles (∼90 nm) with ethylene glycol, nanosheets with surface imperfections (∼41 nm) with urea-ethylene glycol mixture, flower-like structures with citric acid, and nanorods (∼640 nm) with ammonium hydroxide, were produced. The crystallite sizes determined using the Scherrer equation range between 21.38 nm to 47.17 nm. The photocatalytic activity of the modified ZnO nanoparticles, evaluated from their degradation percentages, ranged from a minimum of 58.92% to a maximum of 94.80%. The findings emphasize the importance of organic modifiers in modifying the morphology, crystallinity, and photocatalytic effectiveness of ZnO nanoparticles, providing useful insights for creating new photocatalysts with excellent performance.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100901"},"PeriodicalIF":2.8,"publicationDate":"2025-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145883436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Strategies for optimized microstructure evolution during sintering 烧结过程微观结构演化优化策略
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-17 DOI: 10.1016/j.oceram.2025.100900
Friedrich Raether, Gerhard Seifert
A novel integrated microstructure model on sintering (IMS) was recently introduced. It deals with solid state sintering processes and includes grain boundary and surface diffusion as well as grain growth. To obtain a realistic simulation, the model combines four established approaches: 1. analytical sintering equations, 2. an ideal sintering model for interface energy minimization, 3. a Monte Carlo model for atomic diffusion processes and 4. a model for particle rearrangement. Compared to a previous version the IMS algorithm has been significantly improved and extended. Among other things, grain growth can now be simulated under realistic conditions and particle rotations are considered. The model is presented in detail. Simulation results allow conclusions on practical strategies to improve homogeneity and reduce grain growth during sintering.
介绍了一种新的烧结综合微观结构模型(IMS)。它处理固态烧结过程,包括晶界和表面扩散以及晶粒生长。为了获得真实的仿真,该模型结合了四种已建立的方法:1。解析烧结方程,2。界面能量最小化的理想烧结模型;3 .原子扩散过程的蒙特卡罗模型;粒子重排模型。与以前的版本相比,IMS算法得到了显著的改进和扩展。除其他外,现在可以在现实条件下模拟晶粒生长,并考虑颗粒旋转。详细介绍了该模型。模拟结果得出了改善烧结均匀性和减少晶粒生长的实用策略。
{"title":"Strategies for optimized microstructure evolution during sintering","authors":"Friedrich Raether,&nbsp;Gerhard Seifert","doi":"10.1016/j.oceram.2025.100900","DOIUrl":"10.1016/j.oceram.2025.100900","url":null,"abstract":"<div><div>A novel integrated microstructure model on sintering (IMS) was recently introduced. It deals with solid state sintering processes and includes grain boundary and surface diffusion as well as grain growth. To obtain a realistic simulation, the model combines four established approaches: 1. analytical sintering equations, 2. an ideal sintering model for interface energy minimization, 3. a Monte Carlo model for atomic diffusion processes and 4. a model for particle rearrangement. Compared to a previous version the IMS algorithm has been significantly improved and extended. Among other things, grain growth can now be simulated under realistic conditions and particle rotations are considered. The model is presented in detail. Simulation results allow conclusions on practical strategies to improve homogeneity and reduce grain growth during sintering.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100900"},"PeriodicalIF":2.8,"publicationDate":"2025-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145839986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
UV-assisted drop casting of photocurable ceramic suspensions: The role of venting and organic additives in dense zirconia beads manufacturing 光固化陶瓷悬浮液的紫外辅助滴铸:排气和有机添加剂在致密氧化锆珠制造中的作用
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-17 DOI: 10.1016/j.oceram.2025.100899
Blanka Seredynska, Karolina Korycka, Radoslaw Zurowski, Pawel Falkowski
UV-assisted drop casting is an effective technique for shaping ceramic beads; however, venting ceramic suspensions remains a critical factor in achieving well-densified structures. This study investigates optimal venting strategies for manufacturing zirconia beads. Four systems were evaluated, differing in the presence of an anti-foaming agent and additional vacuum venting. The viscosity of the suspensions was studied, and then ceramic beads were obtained by the UV-assisted drop casting method. The sintered beads were then analyzed for their sphericity, size distribution, Vickers hardness, fracture toughness and cross-sectional porosity. In addition, the microstructure of the series that was found to be the best was analyzed in detail. As a result of the study, a mixing and venting procedure was selected that minimizes defects and produces zirconia beads with good mechanical properties and uniform morphology.
紫外辅助滴铸是一种有效的陶瓷珠形成型技术;然而,排气陶瓷悬浮液仍然是实现良好致密结构的关键因素。本研究探讨了制造氧化锆珠的最佳排气策略。四种系统进行了评估,不同的是,存在消泡剂和额外的真空排气。对悬浮液的粘度进行了研究,然后采用紫外辅助滴铸法制备了陶瓷微珠。然后对烧结球的球度、尺寸分布、维氏硬度、断裂韧性和截面孔隙率进行了分析。此外,还对优选的系列进行了详细的微观组织分析。作为研究的结果,选择了混合和排气工艺,以最大限度地减少缺陷,并生产出具有良好力学性能和均匀形貌的氧化锆珠。
{"title":"UV-assisted drop casting of photocurable ceramic suspensions: The role of venting and organic additives in dense zirconia beads manufacturing","authors":"Blanka Seredynska,&nbsp;Karolina Korycka,&nbsp;Radoslaw Zurowski,&nbsp;Pawel Falkowski","doi":"10.1016/j.oceram.2025.100899","DOIUrl":"10.1016/j.oceram.2025.100899","url":null,"abstract":"<div><div>UV-assisted drop casting is an effective technique for shaping ceramic beads; however, venting ceramic suspensions remains a critical factor in achieving well-densified structures. This study investigates optimal venting strategies for manufacturing zirconia beads. Four systems were evaluated, differing in the presence of an anti-foaming agent and additional vacuum venting. The viscosity of the suspensions was studied, and then ceramic beads were obtained by the UV-assisted drop casting method. The sintered beads were then analyzed for their sphericity, size distribution, Vickers hardness, fracture toughness and cross-sectional porosity. In addition, the microstructure of the series that was found to be the best was analyzed in detail. As a result of the study, a mixing and venting procedure was selected that minimizes defects and produces zirconia beads with good mechanical properties and uniform morphology.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100899"},"PeriodicalIF":2.8,"publicationDate":"2025-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145839989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A bone-like structure of alginate-hydroxyapatite 3D printed by laser-induced forward transfer 用激光诱导正向转移3D打印海藻酸羟基磷灰石的骨状结构
IF 2.8 Q1 MATERIALS SCIENCE, CERAMICS Pub Date : 2025-12-17 DOI: 10.1016/j.oceram.2025.100898
M. Canillas , J. Navarro , A. Saiz , M.A. Rodríguez , M. Morales , S. Lauzurica , C. Molpeceres
Laser-Induced Forward Transfer (LIFT) is a widely used laser-based technique intended to print materials without modifying their properties. One of the main advantages of this transfer technique is that, properly setting the laser parameters and the structure of the donor substrate, materials with different rheology and even physical state can be printed, ranging from low viscosity newtonian fluids to solid state materials. On the other hand, Blister-Assisted Laser-Induced Forward Transfer (BA-LIFT) is a variant of the standard LIFT, wherein a polyimide layer is interposed between the donor substrate and the material to be printed. This configuration eliminates direct laser-material interaction, thereby mitigating photothermal degradation and, in particular in the case of bioinks containing living cells, preserving cell viability. In addition, as nozzle free technologies both avoid clogging problems when ceramic particles are added in the formulation. In this study, we optimized key parameters for the fabrication of three-dimensional scaffolds composed of alginate and tri-calcium phosphate (ALG–TCP) composites using BA-LIFT. The aim was to engineer bone-mimetic constructs capable of acting as extracellular matrices that support cell adhesion and proliferation. The formulation and curing process were tailored and studied to enhance crosslinking efficiency, improving overall biocompatibility while preserving the mechanical stability in the final structure, and minimizing aggressive conditions during the curing process, allowing good cell viability in case of use the formulation to design an ink within embedded living cells. This study demonstrates that a 0.1 M CaCl₂ solution is sufficient to induced effective gelation. Furthermore, the inclusion of TCP particles (20% wt) enhanced the gelation efficiency (75–95%) via surface-mediated release of Ca2+ ions.
激光诱导正向转移(LIFT)是一种广泛使用的基于激光的技术,旨在打印材料而不改变其特性。这种转移技术的主要优点之一是,适当设置激光参数和供体衬底的结构,可以打印从低粘度牛顿流体到固体材料等具有不同流变甚至物理状态的材料。另一方面,泡罩辅助激光诱导正向转移(BA-LIFT)是标准LIFT的一种变体,其中聚酰亚胺层被插入到供体衬底和待打印材料之间。这种结构消除了激光与材料的直接相互作用,从而减轻了光热降解,特别是在含有活细胞的生物墨水的情况下,保持了细胞的活力。此外,由于无喷嘴技术都避免堵塞问题时,陶瓷颗粒添加到配方。在本研究中,我们优化了BA-LIFT法制备海藻酸盐与磷酸三钙(ALG-TCP)复合材料三维支架的关键参数。目的是设计能够作为细胞外基质支持细胞粘附和增殖的骨模拟结构。对配方和固化工艺进行了量身定制和研究,以提高交联效率,提高整体生物相容性,同时保持最终结构的机械稳定性,并最大限度地减少固化过程中的侵蚀条件,从而在使用配方设计嵌入活细胞内的墨水时具有良好的细胞活力。本研究表明,0.1 M的氯化钙溶液足以诱导有效凝胶化。此外,TCP颗粒(20% wt)通过表面介导的Ca2+离子释放提高了凝胶效率(75-95%)。
{"title":"A bone-like structure of alginate-hydroxyapatite 3D printed by laser-induced forward transfer","authors":"M. Canillas ,&nbsp;J. Navarro ,&nbsp;A. Saiz ,&nbsp;M.A. Rodríguez ,&nbsp;M. Morales ,&nbsp;S. Lauzurica ,&nbsp;C. Molpeceres","doi":"10.1016/j.oceram.2025.100898","DOIUrl":"10.1016/j.oceram.2025.100898","url":null,"abstract":"<div><div>Laser-Induced Forward Transfer (LIFT) is a widely used laser-based technique intended to print materials without modifying their properties. One of the main advantages of this transfer technique is that, properly setting the laser parameters and the structure of the donor substrate, materials with different rheology and even physical state can be printed, ranging from low viscosity newtonian fluids to solid state materials. On the other hand, Blister-Assisted Laser-Induced Forward Transfer (BA-LIFT) is a variant of the standard LIFT, wherein a polyimide layer is interposed between the donor substrate and the material to be printed. This configuration eliminates direct laser-material interaction, thereby mitigating photothermal degradation and, in particular in the case of bioinks containing living cells, preserving cell viability. In addition, as nozzle free technologies both avoid clogging problems when ceramic particles are added in the formulation. In this study, we optimized key parameters for the fabrication of three-dimensional scaffolds composed of alginate and tri-calcium phosphate (ALG–TCP) composites using BA-LIFT. The aim was to engineer bone-mimetic constructs capable of acting as extracellular matrices that support cell adhesion and proliferation. The formulation and curing process were tailored and studied to enhance crosslinking efficiency, improving overall biocompatibility while preserving the mechanical stability in the final structure, and minimizing aggressive conditions during the curing process, allowing good cell viability in case of use the formulation to design an ink within embedded living cells. This study demonstrates that a 0.1 M CaCl₂ solution is sufficient to induced effective gelation. Furthermore, the inclusion of TCP particles (20% wt) enhanced the gelation efficiency (75–95%) via surface-mediated release of Ca<sup>2+</sup> ions.</div></div>","PeriodicalId":34140,"journal":{"name":"Open Ceramics","volume":"25 ","pages":"Article 100898"},"PeriodicalIF":2.8,"publicationDate":"2025-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145790143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Open Ceramics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1