Luminescence properties of Rb4Li2TiOGe4O12 single crystal grown by high-temperature solution growth

IF 2 4区 材料科学 Q3 CRYSTALLOGRAPHY Journal of Crystal Growth Pub Date : 2025-03-18 DOI:10.1016/j.jcrysgro.2025.128143
Tianyu Wang , Chuan Tang , Qian Wu , Wen Li , Zhen Jia , Yuntao Wu , Mingjun Xia
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Abstract

A crack-free Rb4Li2TiOGe4O12 (RLTG) bulk crystal with dimensions up to 43 × 42 × 27 mm3 was grown by the high-temperature solution method and investigated for luminescence properties under UV and X-ray excitation for the first time. RLTG crystal displays an exceptional bluish-green photoluminescence peaking at 481 nm with a photoluminescence quantum yield 55.81 %. The fluorescence of the RLTG crystal comes from the isolated distorted TiO5 square pyramids. The light yield of RLTG crystal was measured to be 12,000 photons/MeV under steady-state X-ray excitation, surpassing that of the commercial scintillator Bi4Ge3O12 (BGO).
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高温溶液生长Rb4Li2TiOGe4O12单晶的发光特性
采用高温溶液法制备了尺寸达43 × 42 × 27 mm3的无裂纹Rb4Li2TiOGe4O12 (RLTG)体晶,并首次对其在紫外和x射线激发下的发光性能进行了研究。RLTG晶体在481 nm处表现出蓝绿色的光致发光峰,光致发光量子产率为55.81%。RLTG晶体的荧光来自于孤立的扭曲的TiO5方形金字塔。在稳态x射线激发下,RLTG晶体的产光率达到12,000光子/MeV,超过了商用闪烁体Bi4Ge3O12 (BGO)。
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文献相关原料
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阿拉丁
GeO2
阿拉丁
Li2CO3
阿拉丁
RbF
来源期刊
Journal of Crystal Growth
Journal of Crystal Growth 化学-晶体学
CiteScore
3.60
自引率
11.10%
发文量
373
审稿时长
65 days
期刊介绍: The journal offers a common reference and publication source for workers engaged in research on the experimental and theoretical aspects of crystal growth and its applications, e.g. in devices. Experimental and theoretical contributions are published in the following fields: theory of nucleation and growth, molecular kinetics and transport phenomena, crystallization in viscous media such as polymers and glasses; crystal growth of metals, minerals, semiconductors, superconductors, magnetics, inorganic, organic and biological substances in bulk or as thin films; molecular beam epitaxy, chemical vapor deposition, growth of III-V and II-VI and other semiconductors; characterization of single crystals by physical and chemical methods; apparatus, instrumentation and techniques for crystal growth, and purification methods; multilayer heterostructures and their characterisation with an emphasis on crystal growth and epitaxial aspects of electronic materials. A special feature of the journal is the periodic inclusion of proceedings of symposia and conferences on relevant aspects of crystal growth.
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