Analysis of Different High-Velocity Thermally Sprayed Coatings to Recover AISI H13 High-Pressure Die Casting Molds

IF 3.3 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Journal of Thermal Spray Technology Pub Date : 2025-02-07 DOI:10.1007/s11666-025-01935-3
Andre Renan Mayer, Willian Rafael de Oliveira, Eriel Biagini Sabino, Hipolito Domingo Carvajal Fals, Stefan Björklund, Shrikant Joshi, Anderson Geraldo Marenda Pukasiewicz
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Abstract

High-pressure die casting (HPDC) is a manufacturing process used in the automotive sector to make high-precision components. Corrosion induced by molten metal and heat-checking cracks are two of main failure modes for die casting molds, changing the die's geometry and surface quality. Thermally sprayed coatings can improve the surface properties and recover the geometry of the die caused by aluminum attack. The main objective of this work is to observe the behavior of the H13, Cr3C2-25NiCr, and WC10Co4Cr coatings deposited by HVOF and HVAF processes in aluminum corrosion and die soldering tests. During corrosion and die soldering tests, chromium carbide in the Cr3C2-25NiCr coating reacts with the molten aluminum, creating a tough intermetallic interface and raising the extraction stress. After tests, it was observed that the WC 10Co 4Cr HVAF coating presented low adhesion to aluminum with no observed coating failure due to the formation of intermetallic. Die soldering tests indicated that the WC 10Co 4Cr coating protects the substrate, resulting in lower extraction stress than H13 base material and other HVOF coatings. It was observed that WC 10Co 4Cr HVAF coating showed results comparable to AlCrN PVD coating.

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不同高速热喷涂涂层对AISI H13高压压铸模具的回收分析
高压压铸(HPDC)是一种用于汽车行业制造高精度部件的制造工艺。金属液腐蚀和热检裂纹是压铸模具的两种主要失效形式,会改变模具的几何形状和表面质量。热喷涂涂层可以改善模具的表面性能,恢复因铝侵蚀而造成的模具的几何形状。本工作的主要目的是观察HVOF和HVAF工艺沉积的H13、Cr3C2-25NiCr和WC10Co4Cr涂层在铝腐蚀和模焊试验中的行为。在腐蚀和模焊试验中,Cr3C2-25NiCr涂层中的碳化铬与铝液发生反应,形成了一个坚韧的金属间界面,提高了萃取应力。试验发现,wc10co 4Cr HVAF涂层对铝的附着力较低,未发现由于金属间化合物的形成导致涂层失效。模焊试验表明,与H13基材和其他HVOF涂层相比,WC 10Co 4Cr涂层可以保护基体,从而产生更低的萃取应力。结果表明,wc10co 4Cr HVAF涂层与AlCrN PVD涂层效果相当。
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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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