Overcoming the energy–water nexus in dry regions – water-positive production of green hydrogen carriers and base chemicals: the DryHy project – technical aspects†

IF 4.1 3区 材料科学 Q2 CHEMISTRY, PHYSICAL Sustainable Energy & Fuels Pub Date : 2025-02-25 DOI:10.1039/D4SE01783H
Victor Selmert, Leandros Paschalidis, Nicolas Kruse, Steffen Dirkes, Ansgar Kretzschmar, Gbenga Jerome, Carl Jung, Lu Xu, Nils Beltermann, Hermann Tempel, Roland Peters, Remzi Can Samsun and Rüdiger-A. Eichel
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Abstract

The application of Direct Air Capture (DAC) for extracting CO2 from the atmosphere has a great potential to reduce net CO2 emissions and help achieve climate goals. Besides storing the separated CO2, it can be used as a carbon feedstock for producing CO2-neutral e-fuels, marking a critical research focus area. Despite advancements in various DAC technologies and processes, their large-scale implementation remains limited, among other reasons, because of the large amounts of energy required to power such processes. This article explores the utilization of DAC for water-conscious production of methanol in sunny regions, using cost-efficient photovoltaic power. The selected approach is presented, which involves a process on demonstrator scale with amine-based DAC for CO2 and water separation from air, high-temperature electrolysis using solid oxide electrolysis cells (SOEC) for syngas production, and subsequent methanol synthesis. We also discuss alternative methods, potential locations, and implementation strategies, highlighting the advantages but also the challenges of producing green methanol in sunny regions outside Germany.

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克服干旱地区的能源-水关系-绿色氢载体和基础化学品的水积极生产:DryHy项目-技术方面†
直接空气捕集(DAC)技术用于从大气中提取二氧化碳,在减少二氧化碳净排放和帮助实现气候目标方面具有巨大的潜力。除了储存分离的二氧化碳外,它还可以用作生产二氧化碳中性电子燃料的碳原料,这标志着一个关键的研究重点领域。尽管各种DAC技术和工艺取得了进步,但它们的大规模实施仍然有限,其中一个原因是需要大量的能源来为这些工艺提供动力。本文探讨了在阳光充足的地区,利用成本效益高的光伏发电,将DAC用于节水生产甲醇。所选择的方法包括一个示范规模的过程,以胺基DAC从空气中分离二氧化碳和水,使用固体氧化物电解电池(SOEC)进行高温电解以生产合成气,以及随后的甲醇合成。我们还讨论了替代方法、潜在地点和实施策略,强调了在德国以外阳光充足的地区生产绿色甲醇的优势和挑战。
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来源期刊
Sustainable Energy & Fuels
Sustainable Energy & Fuels Energy-Energy Engineering and Power Technology
CiteScore
10.00
自引率
3.60%
发文量
394
期刊介绍: Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.
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